Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)

In the mol­ecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)(2)(H(2)O)(2)](ClO(4))(2) [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C(12)H(10)N(6))], the central Ni(II) atom is six-coordinated by a pair of chelating 2-bpt ligands and two water mol­ecules. Inter­molecular O—...

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Detalles Bibliográficos
Autores principales: Shao, Chun-Fu, Geng, Li-Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977572/
https://www.ncbi.nlm.nih.gov/pubmed/21583758
http://dx.doi.org/10.1107/S1600536809012598
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author Shao, Chun-Fu
Geng, Li-Chuan
author_facet Shao, Chun-Fu
Geng, Li-Chuan
author_sort Shao, Chun-Fu
collection PubMed
description In the mol­ecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)(2)(H(2)O)(2)](ClO(4))(2) [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C(12)H(10)N(6))], the central Ni(II) atom is six-coordinated by a pair of chelating 2-bpt ligands and two water mol­ecules. Inter­molecular O—H⋯N inter­actions link the monomeric units into a two-dimensional hydrogen-bonded (4,4) network, which is extended to a three-dimensional supra­molecular aggregate via π⋯π stacking inter­actions [centroid–centroid distances 3.809 (3) and 3.499 (3)  Å].
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spelling pubmed-29775722010-12-30 Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate) Shao, Chun-Fu Geng, Li-Chuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)(2)(H(2)O)(2)](ClO(4))(2) [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C(12)H(10)N(6))], the central Ni(II) atom is six-coordinated by a pair of chelating 2-bpt ligands and two water mol­ecules. Inter­molecular O—H⋯N inter­actions link the monomeric units into a two-dimensional hydrogen-bonded (4,4) network, which is extended to a three-dimensional supra­molecular aggregate via π⋯π stacking inter­actions [centroid–centroid distances 3.809 (3) and 3.499 (3)  Å]. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977572/ /pubmed/21583758 http://dx.doi.org/10.1107/S1600536809012598 Text en © Shao and Geng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shao, Chun-Fu
Geng, Li-Chuan
Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_full Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_fullStr Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_full_unstemmed Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_short Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_sort bis(4-amino-3,5-di-2-pyridyl-4h-1,2,4-triazole)diaquanickel(ii) bis(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977572/
https://www.ncbi.nlm.nih.gov/pubmed/21583758
http://dx.doi.org/10.1107/S1600536809012598
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