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Diaquabis(2-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))manganese(II)
In the monomeric title complex, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chlorobenzoate (CB) ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule, all...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977573/ https://www.ncbi.nlm.nih.gov/pubmed/21583759 http://dx.doi.org/10.1107/S160053680901318X |
Sumario: | In the monomeric title complex, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Mn(II) atom is located on a crystallographic centre of inversion. The asymmetric unit contains one 2-chlorobenzoate (CB) ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 77.9 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 45.94 (5)°. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules into infinite chains. |
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