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{6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate
In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetradentate Schiff base ligand. The asymmetric unit comprises one complex molecule and a water molecule of crystallization. The water H atoms form bifurca...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977574/ https://www.ncbi.nlm.nih.gov/pubmed/21583760 http://dx.doi.org/10.1107/S1600536809012859 |
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author | Kargar, Hadi Kia, Reza Fun, Hoong-Kun Jamshidvand, Arezoo |
author_facet | Kargar, Hadi Kia, Reza Fun, Hoong-Kun Jamshidvand, Arezoo |
author_sort | Kargar, Hadi |
collection | PubMed |
description | In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetradentate Schiff base ligand. The asymmetric unit comprises one complex molecule and a water molecule of crystallization. The water H atoms form bifurcated O—H⋯(O,O) intermolecular hydrogen bonds with the O atoms of the phenolate and ethoxy groups with R(1)(2)(5) and R(1)(2)(6) ring motifs, which may, in part, influence the molecular configuration. The dihedral angle between the two O—Cu—N coordination planes is 31.02 (6)° and the dihedral angle between the two benzene rings is 34.98 (7)°. In the crystal structure, molecules are linked together by intermolecular C—H⋯O interactions, forming extended chains along the a axis. The crystal structure is further stabilized by intermolecular C—H⋯π and π–π [centroid–centroid = 3.5068 (13) Å] interactions. |
format | Text |
id | pubmed-2977574 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29775742010-12-30 {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate Kargar, Hadi Kia, Reza Fun, Hoong-Kun Jamshidvand, Arezoo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetradentate Schiff base ligand. The asymmetric unit comprises one complex molecule and a water molecule of crystallization. The water H atoms form bifurcated O—H⋯(O,O) intermolecular hydrogen bonds with the O atoms of the phenolate and ethoxy groups with R(1)(2)(5) and R(1)(2)(6) ring motifs, which may, in part, influence the molecular configuration. The dihedral angle between the two O—Cu—N coordination planes is 31.02 (6)° and the dihedral angle between the two benzene rings is 34.98 (7)°. In the crystal structure, molecules are linked together by intermolecular C—H⋯O interactions, forming extended chains along the a axis. The crystal structure is further stabilized by intermolecular C—H⋯π and π–π [centroid–centroid = 3.5068 (13) Å] interactions. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977574/ /pubmed/21583760 http://dx.doi.org/10.1107/S1600536809012859 Text en © Kargar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Fun, Hoong-Kun Jamshidvand, Arezoo {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate |
title | {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate |
title_full | {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate |
title_fullStr | {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate |
title_full_unstemmed | {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate |
title_short | {6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) monohydrate |
title_sort | {6,6′-diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977574/ https://www.ncbi.nlm.nih.gov/pubmed/21583760 http://dx.doi.org/10.1107/S1600536809012859 |
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