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{6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate

In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetra­dentate Schiff base ligand. The asymmetric unit comprises one complex mol­ecule and a water mol­ecule of crystallization. The water H atoms form bifurca...

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Autores principales: Kargar, Hadi, Kia, Reza, Fun, Hoong-Kun, Jamshidvand, Arezoo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977574/
https://www.ncbi.nlm.nih.gov/pubmed/21583760
http://dx.doi.org/10.1107/S1600536809012859
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author Kargar, Hadi
Kia, Reza
Fun, Hoong-Kun
Jamshidvand, Arezoo
author_facet Kargar, Hadi
Kia, Reza
Fun, Hoong-Kun
Jamshidvand, Arezoo
author_sort Kargar, Hadi
collection PubMed
description In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetra­dentate Schiff base ligand. The asymmetric unit comprises one complex mol­ecule and a water mol­ecule of crystallization. The water H atoms form bifurcated O—H⋯(O,O) inter­molecular hydrogen bonds with the O atoms of the phenolate and eth­oxy groups with R(1)(2)(5) and R(1)(2)(6) ring motifs, which may, in part, influence the mol­ecular configuration. The dihedral angle between the two O—Cu—N coordination planes is 31.02 (6)° and the dihedral angle between the two benzene rings is 34.98 (7)°. In the crystal structure, mol­ecules are linked together by inter­molecular C—H⋯O inter­actions, forming extended chains along the a axis. The crystal structure is further stabilized by inter­molecular C—H⋯π and π–π [centroid–centroid = 3.5068 (13) Å] inter­actions.
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spelling pubmed-29775742010-12-30 {6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate Kargar, Hadi Kia, Reza Fun, Hoong-Kun Jamshidvand, Arezoo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, the Cu(II) ion has a distorted planar geometry, coordinated by the N(2)O(2) unit of the tetra­dentate Schiff base ligand. The asymmetric unit comprises one complex mol­ecule and a water mol­ecule of crystallization. The water H atoms form bifurcated O—H⋯(O,O) inter­molecular hydrogen bonds with the O atoms of the phenolate and eth­oxy groups with R(1)(2)(5) and R(1)(2)(6) ring motifs, which may, in part, influence the mol­ecular configuration. The dihedral angle between the two O—Cu—N coordination planes is 31.02 (6)° and the dihedral angle between the two benzene rings is 34.98 (7)°. In the crystal structure, mol­ecules are linked together by inter­molecular C—H⋯O inter­actions, forming extended chains along the a axis. The crystal structure is further stabilized by inter­molecular C—H⋯π and π–π [centroid–centroid = 3.5068 (13) Å] inter­actions. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977574/ /pubmed/21583760 http://dx.doi.org/10.1107/S1600536809012859 Text en © Kargar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Fun, Hoong-Kun
Jamshidvand, Arezoo
{6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate
title {6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate
title_full {6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate
title_fullStr {6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate
title_full_unstemmed {6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate
title_short {6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) monohydrate
title_sort {6,6′-dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977574/
https://www.ncbi.nlm.nih.gov/pubmed/21583760
http://dx.doi.org/10.1107/S1600536809012859
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