Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]

In the title compound, {[Zn(C(9)H(9)N(5))(2)(H(2)O)(2)](ClO(4))(2)}(n), the Zn(II) ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyrid­yl)ethyl­idene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coor...

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Detalles Bibliográficos
Autores principales: Sun, Xiaodan, He, Xianhua, Wang, Wei, Miao, Donghua, Sun, Qiaozhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977576/
https://www.ncbi.nlm.nih.gov/pubmed/21583762
http://dx.doi.org/10.1107/S1600536809013130
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author Sun, Xiaodan
He, Xianhua
Wang, Wei
Miao, Donghua
Sun, Qiaozhen
author_facet Sun, Xiaodan
He, Xianhua
Wang, Wei
Miao, Donghua
Sun, Qiaozhen
author_sort Sun, Xiaodan
collection PubMed
description In the title compound, {[Zn(C(9)H(9)N(5))(2)(H(2)O)(2)](ClO(4))(2)}(n), the Zn(II) ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyrid­yl)ethyl­idene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coordinated water mol­ecules in a slightly distorted octa­hedral environment. Each L ligand bridges symmetry-related Zn(II) ions, forming a two-dimensional layer with a (4,4) grid. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect perchlorate counter-anions to the layers.
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spelling pubmed-29775762010-12-30 Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)] Sun, Xiaodan He, Xianhua Wang, Wei Miao, Donghua Sun, Qiaozhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(9)H(9)N(5))(2)(H(2)O)(2)](ClO(4))(2)}(n), the Zn(II) ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyrid­yl)ethyl­idene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coordinated water mol­ecules in a slightly distorted octa­hedral environment. Each L ligand bridges symmetry-related Zn(II) ions, forming a two-dimensional layer with a (4,4) grid. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect perchlorate counter-anions to the layers. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977576/ /pubmed/21583762 http://dx.doi.org/10.1107/S1600536809013130 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Xiaodan
He, Xianhua
Wang, Wei
Miao, Donghua
Sun, Qiaozhen
Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]
title Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]
title_full Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]
title_fullStr Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]
title_full_unstemmed Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]
title_short Poly[[diaqua­{N-[1-(3-pyrid­yl)ethyl­idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis­(perchlorate)]
title_sort poly[[diaqua­{n-[1-(3-pyrid­yl)ethyl­idene]-4h-1,2,4-triazol-4-amine}zinc(ii)] bis­(perchlorate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977576/
https://www.ncbi.nlm.nih.gov/pubmed/21583762
http://dx.doi.org/10.1107/S1600536809013130
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AT sunqiaozhen polydiaquan13pyridylethylidene4h124triazol4aminezinciibisperchlorate

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