catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]

The title compound, {[Cu(2)(C(17)H(11)N(3)O)(SO(4))(C(5)H(5)N)(2)]·0.5C(4)H(10)O}(n), was syn­thesized by the reaction of 2-hydr­oxy-1-naphthyl­aldehyde-2-pyridine­carboxyl­hydrazone with copper sulfonate. A one-dimensional polymer was obtained via self-assembly. Each Cu ion is located in a distorte...

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Detalles Bibliográficos
Autores principales: Wang, Quanchang, Li, Dacheng, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977577/
https://www.ncbi.nlm.nih.gov/pubmed/21583763
http://dx.doi.org/10.1107/S1600536809012653
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author Wang, Quanchang
Li, Dacheng
Wang, Daqi
author_facet Wang, Quanchang
Li, Dacheng
Wang, Daqi
author_sort Wang, Quanchang
collection PubMed
description The title compound, {[Cu(2)(C(17)H(11)N(3)O)(SO(4))(C(5)H(5)N)(2)]·0.5C(4)H(10)O}(n), was syn­thesized by the reaction of 2-hydr­oxy-1-naphthyl­aldehyde-2-pyridine­carboxyl­hydrazone with copper sulfonate. A one-dimensional polymer was obtained via self-assembly. Each Cu ion is located in a distorted square-pyramidal coordination environment, with one Cu ion coordinated by two N and three O atoms, while the other links to two O and three N atoms. In the crystal, weak inter­molecular C—H⋯O inter­actions connect the chains into a two-dimensional network.
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spelling pubmed-29775772010-12-30 catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate] Wang, Quanchang Li, Dacheng Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Cu(2)(C(17)H(11)N(3)O)(SO(4))(C(5)H(5)N)(2)]·0.5C(4)H(10)O}(n), was syn­thesized by the reaction of 2-hydr­oxy-1-naphthyl­aldehyde-2-pyridine­carboxyl­hydrazone with copper sulfonate. A one-dimensional polymer was obtained via self-assembly. Each Cu ion is located in a distorted square-pyramidal coordination environment, with one Cu ion coordinated by two N and three O atoms, while the other links to two O and three N atoms. In the crystal, weak inter­molecular C—H⋯O inter­actions connect the chains into a two-dimensional network. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977577/ /pubmed/21583763 http://dx.doi.org/10.1107/S1600536809012653 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Quanchang
Li, Dacheng
Wang, Daqi
catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
title catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
title_full catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
title_fullStr catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
title_full_unstemmed catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
title_short catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
title_sort catena-poly[[[pyridinecopper(ii)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico­linoylhydrazonato)-[pyridinecopper(ii)]-μ-sulfato] diethyl ether hemisolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977577/
https://www.ncbi.nlm.nih.gov/pubmed/21583763
http://dx.doi.org/10.1107/S1600536809012653
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AT lidacheng catenapolypyridinecopperiim2oxidonaphthalene1carbaldehydepicolinoylhydrazonatopyridinecopperiimsulfatodiethyletherhemisolvate
AT wangdaqi catenapolypyridinecopperiim2oxidonaphthalene1carbaldehydepicolinoylhydrazonatopyridinecopperiimsulfatodiethyletherhemisolvate

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