[μ-10,21-Dimethyl-3,6,14,17-tetra­aza­tricyclo­[17.3.1.1(8,12)]tetra­cosa-1(23),8(24),9,11,19,21-hexa­ene-23,24-diolato-κ(8) N (3),N (6),O (23),O (24):N (14),N (17),O (23),O (24)]bis­[(nitrato-κ(2) O,O′)nickel(II)]

In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bri...

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Detalles Bibliográficos
Autores principales: Li, Quan-Jun, Ma, Jian-Fang, Liu, Jie, Han, Ting-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977579/
https://www.ncbi.nlm.nih.gov/pubmed/21583765
http://dx.doi.org/10.1107/S1600536809010174
Descripción
Sumario:In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni(2)O(2) ring.

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