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[μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8) N (3),N (6),O (23),O (24):N (14),N (17),O (23),O (24)]bis[(nitrato-κ(2) O,O′)nickel(II)]
In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octahedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bri...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977579/ https://www.ncbi.nlm.nih.gov/pubmed/21583765 http://dx.doi.org/10.1107/S1600536809010174 |
| _version_ | 1782191138125381632 |
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| author | Li, Quan-Jun Ma, Jian-Fang Liu, Jie Han, Ting-Ting |
| author_facet | Li, Quan-Jun Ma, Jian-Fang Liu, Jie Han, Ting-Ting |
| author_sort | Li, Quan-Jun |
| collection | PubMed |
| description | In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octahedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni(2)O(2) ring. |
| format | Text |
| id | pubmed-2977579 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775792010-12-30 [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8) N (3),N (6),O (23),O (24):N (14),N (17),O (23),O (24)]bis[(nitrato-κ(2) O,O′)nickel(II)] Li, Quan-Jun Ma, Jian-Fang Liu, Jie Han, Ting-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octahedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni(2)O(2) ring. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977579/ /pubmed/21583765 http://dx.doi.org/10.1107/S1600536809010174 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Quan-Jun Ma, Jian-Fang Liu, Jie Han, Ting-Ting [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8) N (3),N (6),O (23),O (24):N (14),N (17),O (23),O (24)]bis[(nitrato-κ(2) O,O′)nickel(II)] |
| title | [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8)
N
(3),N
(6),O
(23),O
(24):N
(14),N
(17),O
(23),O
(24)]bis[(nitrato-κ(2)
O,O′)nickel(II)] |
| title_full | [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8)
N
(3),N
(6),O
(23),O
(24):N
(14),N
(17),O
(23),O
(24)]bis[(nitrato-κ(2)
O,O′)nickel(II)] |
| title_fullStr | [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8)
N
(3),N
(6),O
(23),O
(24):N
(14),N
(17),O
(23),O
(24)]bis[(nitrato-κ(2)
O,O′)nickel(II)] |
| title_full_unstemmed | [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8)
N
(3),N
(6),O
(23),O
(24):N
(14),N
(17),O
(23),O
(24)]bis[(nitrato-κ(2)
O,O′)nickel(II)] |
| title_short | [μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8)
N
(3),N
(6),O
(23),O
(24):N
(14),N
(17),O
(23),O
(24)]bis[(nitrato-κ(2)
O,O′)nickel(II)] |
| title_sort | [μ-10,21-dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1(8,12)]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ(8)
n
(3),n
(6),o
(23),o
(24):n
(14),n
(17),o
(23),o
(24)]bis[(nitrato-κ(2)
o,o′)nickel(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977579/ https://www.ncbi.nlm.nih.gov/pubmed/21583765 http://dx.doi.org/10.1107/S1600536809010174 |
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