mer-(3,5-Dichloro-2-oxidobenzaldehyde thio­semicarbazonato-κ(3) S,N (1),O)(methanol-κO)(1,10-phenanthroline-κ(2) N,N′)nickel(II)

In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa­hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio­semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. Th...

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Detalles Bibliográficos
Autores principales: Gao, J. Y., Liu, Z., Wang, Y.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977580/
https://www.ncbi.nlm.nih.gov/pubmed/21583766
http://dx.doi.org/10.1107/S1600536809013208
Descripción
Sumario:In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa­hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio­semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N—H⋯Cl, N—H⋯N, C—H⋯S and O—H⋯S hydrogen bonds.

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