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mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) S,N (1),O)(methanol-κO)(1,10-phenanthroline-κ(2) N,N′)nickel(II)
In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octahedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thiosemicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. Th...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977580/ https://www.ncbi.nlm.nih.gov/pubmed/21583766 http://dx.doi.org/10.1107/S1600536809013208 |
| _version_ | 1782191138380185600 |
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| author | Gao, J. Y. Liu, Z. Wang, Y. |
| author_facet | Gao, J. Y. Liu, Z. Wang, Y. |
| author_sort | Gao, J. Y. |
| collection | PubMed |
| description | In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octahedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thiosemicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N—H⋯Cl, N—H⋯N, C—H⋯S and O—H⋯S hydrogen bonds. |
| format | Text |
| id | pubmed-2977580 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775802010-12-30 mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) S,N (1),O)(methanol-κO)(1,10-phenanthroline-κ(2) N,N′)nickel(II) Gao, J. Y. Liu, Z. Wang, Y. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octahedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thiosemicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N—H⋯Cl, N—H⋯N, C—H⋯S and O—H⋯S hydrogen bonds. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977580/ /pubmed/21583766 http://dx.doi.org/10.1107/S1600536809013208 Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, J. Y. Liu, Z. Wang, Y. mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) S,N (1),O)(methanol-κO)(1,10-phenanthroline-κ(2) N,N′)nickel(II) |
| title |
mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
S,N
(1),O)(methanol-κO)(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
| title_full |
mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
S,N
(1),O)(methanol-κO)(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
| title_fullStr |
mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
S,N
(1),O)(methanol-κO)(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
| title_full_unstemmed |
mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
S,N
(1),O)(methanol-κO)(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
| title_short |
mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
S,N
(1),O)(methanol-κO)(1,10-phenanthroline-κ(2)
N,N′)nickel(II) |
| title_sort | mer-(3,5-dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
s,n
(1),o)(methanol-κo)(1,10-phenanthroline-κ(2)
n,n′)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977580/ https://www.ncbi.nlm.nih.gov/pubmed/21583766 http://dx.doi.org/10.1107/S1600536809013208 |
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