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Aqua(2,2′-bipyrimidine-κ(2) N,N′)(succinato-κ(2) O (1),O (4))copper(II) dihydrate
In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water molecule in the apical position completes the slightly distorted square-pyramidal coordin...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977583/ https://www.ncbi.nlm.nih.gov/pubmed/21583769 http://dx.doi.org/10.1107/S1600536809013518 |
Sumario: | In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water molecule in the apical position completes the slightly distorted square-pyramidal coordination geometry. Another carboxylate O atom from an adjacent complex is located in the opposite apical direction, with a Cu⋯O distance of 2.706 (3) Å, and is not considered as a bridging atom. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. |
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