Cargando…

Aqua­(2,2′-bipyrimidine-κ(2) N,N′)(succin­ato-κ(2) O (1),O (4))copper(II) dihydrate

In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water mol­ecule in the apical position completes the slightly distorted square-pyramidal coordin...

Descripción completa

Detalles Bibliográficos
Autores principales: Ke, Xi-Jun, Li, Dong-Sheng, Zhao, Jun, He, Qiu-Fen, Li, Cai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977583/
https://www.ncbi.nlm.nih.gov/pubmed/21583769
http://dx.doi.org/10.1107/S1600536809013518
Descripción
Sumario:In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water mol­ecule in the apical position completes the slightly distorted square-pyramidal coordination geometry. Another carboxyl­ate O atom from an adjacent complex is located in the opposite apical direction, with a Cu⋯O distance of 2.706 (3) Å, and is not considered as a bridging atom. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure.