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Aqua(2,2′-bipyrimidine-κ(2) N,N′)(succinato-κ(2) O (1),O (4))copper(II) dihydrate
In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water molecule in the apical position completes the slightly distorted square-pyramidal coordin...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977583/ https://www.ncbi.nlm.nih.gov/pubmed/21583769 http://dx.doi.org/10.1107/S1600536809013518 |
| _version_ | 1782191139081682944 |
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| author | Ke, Xi-Jun Li, Dong-Sheng Zhao, Jun He, Qiu-Fen Li, Cai |
| author_facet | Ke, Xi-Jun Li, Dong-Sheng Zhao, Jun He, Qiu-Fen Li, Cai |
| author_sort | Ke, Xi-Jun |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water molecule in the apical position completes the slightly distorted square-pyramidal coordination geometry. Another carboxylate O atom from an adjacent complex is located in the opposite apical direction, with a Cu⋯O distance of 2.706 (3) Å, and is not considered as a bridging atom. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. |
| format | Text |
| id | pubmed-2977583 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775832010-12-30 Aqua(2,2′-bipyrimidine-κ(2) N,N′)(succinato-κ(2) O (1),O (4))copper(II) dihydrate Ke, Xi-Jun Li, Dong-Sheng Zhao, Jun He, Qiu-Fen Li, Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(4)H(4)O(4))(C(8)H(6)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water molecule in the apical position completes the slightly distorted square-pyramidal coordination geometry. Another carboxylate O atom from an adjacent complex is located in the opposite apical direction, with a Cu⋯O distance of 2.706 (3) Å, and is not considered as a bridging atom. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977583/ /pubmed/21583769 http://dx.doi.org/10.1107/S1600536809013518 Text en © Ke et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ke, Xi-Jun Li, Dong-Sheng Zhao, Jun He, Qiu-Fen Li, Cai Aqua(2,2′-bipyrimidine-κ(2) N,N′)(succinato-κ(2) O (1),O (4))copper(II) dihydrate |
| title | Aqua(2,2′-bipyrimidine-κ(2)
N,N′)(succinato-κ(2)
O
(1),O
(4))copper(II) dihydrate |
| title_full | Aqua(2,2′-bipyrimidine-κ(2)
N,N′)(succinato-κ(2)
O
(1),O
(4))copper(II) dihydrate |
| title_fullStr | Aqua(2,2′-bipyrimidine-κ(2)
N,N′)(succinato-κ(2)
O
(1),O
(4))copper(II) dihydrate |
| title_full_unstemmed | Aqua(2,2′-bipyrimidine-κ(2)
N,N′)(succinato-κ(2)
O
(1),O
(4))copper(II) dihydrate |
| title_short | Aqua(2,2′-bipyrimidine-κ(2)
N,N′)(succinato-κ(2)
O
(1),O
(4))copper(II) dihydrate |
| title_sort | aqua(2,2′-bipyrimidine-κ(2)
n,n′)(succinato-κ(2)
o
(1),o
(4))copper(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977583/ https://www.ncbi.nlm.nih.gov/pubmed/21583769 http://dx.doi.org/10.1107/S1600536809013518 |
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