Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate

In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo­penta­dienyl C atom 0.4222 (4) Å out of plane. The di...

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Autores principales: Hao, Xin-Qi, Li, Hong-Mei, Jiang, Hui, Ma, Yong-Tao, Song, Mao-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977585/
https://www.ncbi.nlm.nih.gov/pubmed/21583771
http://dx.doi.org/10.1107/S1600536809012884
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author Hao, Xin-Qi
Li, Hong-Mei
Jiang, Hui
Ma, Yong-Tao
Song, Mao-Ping
author_facet Hao, Xin-Qi
Li, Hong-Mei
Jiang, Hui
Ma, Yong-Tao
Song, Mao-Ping
author_sort Hao, Xin-Qi
collection PubMed
description In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo­penta­dienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo­penta­dienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C—H⋯π contact via a crystallographic inversion centre, while the C—H⋯Cl contacts in the dimeric centre link the dichlormethane mol­ecules with the Pd complex mol­ecules.
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spelling pubmed-29775852010-12-30 Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate Hao, Xin-Qi Li, Hong-Mei Jiang, Hui Ma, Yong-Tao Song, Mao-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo­penta­dienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo­penta­dienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C—H⋯π contact via a crystallographic inversion centre, while the C—H⋯Cl contacts in the dimeric centre link the dichlormethane mol­ecules with the Pd complex mol­ecules. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977585/ /pubmed/21583771 http://dx.doi.org/10.1107/S1600536809012884 Text en © Hao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Xin-Qi
Li, Hong-Mei
Jiang, Hui
Ma, Yong-Tao
Song, Mao-Ping
Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate
title Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate
title_full Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate
title_fullStr Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate
title_full_unstemmed Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate
title_short Bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) C (1),N]palladium(II) dichloro­methane solvate
title_sort bromido{dicyclo­hexyl[2′-(dimethyl­amino)biphenyl-2-yl]phosphine-κp}[2-(4,6-dimethyl­pyrimidin-2-yl)ferrocenyl-κ(2) c (1),n]palladium(ii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977585/
https://www.ncbi.nlm.nih.gov/pubmed/21583771
http://dx.doi.org/10.1107/S1600536809012884
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