Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate

In the title compound, [Fe(C(5)H(5))(C(20)H(21)N(2)O(4))], the pyrrolidine ring exhibits an envelope conformation with the spiro-C atom deviating from the plane of the remaining four atoms. The pyrrolidine ring is almost perpendicular to the indolinone ring [dihedral angle = 87.52 (7)°]. The structu...

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Autores principales: Kamala, E. Theboral Sugi, Nirmala, S., Sudha, L., Kathiravan, S., Raghunathan, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977586/
https://www.ncbi.nlm.nih.gov/pubmed/21583772
http://dx.doi.org/10.1107/S1600536809012756
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author Kamala, E. Theboral Sugi
Nirmala, S.
Sudha, L.
Kathiravan, S.
Raghunathan, R.
author_facet Kamala, E. Theboral Sugi
Nirmala, S.
Sudha, L.
Kathiravan, S.
Raghunathan, R.
author_sort Kamala, E. Theboral Sugi
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(20)H(21)N(2)O(4))], the pyrrolidine ring exhibits an envelope conformation with the spiro-C atom deviating from the plane of the remaining four atoms. The pyrrolidine ring is almost perpendicular to the indolinone ring [dihedral angle = 87.52 (7)°]. The structure is stabilized by an intra­molecular O—H⋯N hydrogen bond and by inter­molecular C—H⋯O and N—H⋯O inter­actions.
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spelling pubmed-29775862010-12-30 Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Kathiravan, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(20)H(21)N(2)O(4))], the pyrrolidine ring exhibits an envelope conformation with the spiro-C atom deviating from the plane of the remaining four atoms. The pyrrolidine ring is almost perpendicular to the indolinone ring [dihedral angle = 87.52 (7)°]. The structure is stabilized by an intra­molecular O—H⋯N hydrogen bond and by inter­molecular C—H⋯O and N—H⋯O inter­actions. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977586/ /pubmed/21583772 http://dx.doi.org/10.1107/S1600536809012756 Text en © Kamala et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kamala, E. Theboral Sugi
Nirmala, S.
Sudha, L.
Kathiravan, S.
Raghunathan, R.
Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
title Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
title_full Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
title_fullStr Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
title_full_unstemmed Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
title_short Methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
title_sort methyl 3-[ferrocen­yl(hydr­oxy)meth­yl]-1-methyl-2′-oxospiro­[pyrrolidine-2,3′-indoline]-3-carboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977586/
https://www.ncbi.nlm.nih.gov/pubmed/21583772
http://dx.doi.org/10.1107/S1600536809012756
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AT sudhal methyl3ferrocenylhydroxymethyl1methyl2oxospiropyrrolidine23indoline3carboxylate
AT kathiravans methyl3ferrocenylhydroxymethyl1methyl2oxospiropyrrolidine23indoline3carboxylate
AT raghunathanr methyl3ferrocenylhydroxymethyl1methyl2oxospiropyrrolidine23indoline3carboxylate

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