catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]

In the title compound, [ZnCl(2)(C(16)H(20)N(4))](n), tetra­hedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis­(3-pyridylmeth­yl)­piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of [ZnCl(2)(3-bpmp)](n) chains situa...

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Detalles Bibliográficos
Autores principales: Hardy, Aaron M., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977589/
https://www.ncbi.nlm.nih.gov/pubmed/21583775
http://dx.doi.org/10.1107/S1600536809013877
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author Hardy, Aaron M.
LaDuca, Robert L.
author_facet Hardy, Aaron M.
LaDuca, Robert L.
author_sort Hardy, Aaron M.
collection PubMed
description In the title compound, [ZnCl(2)(C(16)H(20)N(4))](n), tetra­hedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis­(3-pyridylmeth­yl)­piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of [ZnCl(2)(3-bpmp)](n) chains situated parallel to ([Image: see text]02). These chains aggregate via C—H⋯Cl inter­actions to form supra­molecular layers, which in turn stack to construct the three-dimensional crystal structure.
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spelling pubmed-29775892010-12-30 catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine] Hardy, Aaron M. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(16)H(20)N(4))](n), tetra­hedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis­(3-pyridylmeth­yl)­piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of [ZnCl(2)(3-bpmp)](n) chains situated parallel to ([Image: see text]02). These chains aggregate via C—H⋯Cl inter­actions to form supra­molecular layers, which in turn stack to construct the three-dimensional crystal structure. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977589/ /pubmed/21583775 http://dx.doi.org/10.1107/S1600536809013877 Text en © Hardy and LaDuca 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hardy, Aaron M.
LaDuca, Robert L.
catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
title catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
title_full catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
title_fullStr catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
title_full_unstemmed catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
title_short catena-Poly[[dichloridozinc(II)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
title_sort catena-poly[[dichloridozinc(ii)]-μ-1,4-bis­(3-pyridylmeth­yl)piperazine]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977589/
https://www.ncbi.nlm.nih.gov/pubmed/21583775
http://dx.doi.org/10.1107/S1600536809013877
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