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Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)}
The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphthoxyacetate anion and one water molecule in a distorted ZnO(4) tetrahedral geometry. The naphthalene system of...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977591/ https://www.ncbi.nlm.nih.gov/pubmed/21583777 http://dx.doi.org/10.1107/S1600536809013750 |
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author | Chen, Fang-Jun Xu, Hai Xu, Hui Huang, Ke-Long |
author_facet | Chen, Fang-Jun Xu, Hai Xu, Hui Huang, Ke-Long |
author_sort | Chen, Fang-Jun |
collection | PubMed |
description | The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphthoxyacetate anion and one water molecule in a distorted ZnO(4) tetrahedral geometry. The naphthalene system of the bridging ligand is nearly perpendicular to the naphthalene of the terminal ligand, with a dihedral angle of 78.26 (6)°. Within the binuclear molecule the Zn⋯Zn separation is 3.815 (5) Å. In the crystal structure, intermolecular O—H⋯O hydrogen bonding between the water molecule and carboxylate groups helps to stabilize the crystal structure. |
format | Text |
id | pubmed-2977591 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29775912010-12-30 Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} Chen, Fang-Jun Xu, Hai Xu, Hui Huang, Ke-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphthoxyacetate anion and one water molecule in a distorted ZnO(4) tetrahedral geometry. The naphthalene system of the bridging ligand is nearly perpendicular to the naphthalene of the terminal ligand, with a dihedral angle of 78.26 (6)°. Within the binuclear molecule the Zn⋯Zn separation is 3.815 (5) Å. In the crystal structure, intermolecular O—H⋯O hydrogen bonding between the water molecule and carboxylate groups helps to stabilize the crystal structure. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977591/ /pubmed/21583777 http://dx.doi.org/10.1107/S1600536809013750 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Fang-Jun Xu, Hai Xu, Hui Huang, Ke-Long Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} |
title | Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} |
title_full | Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} |
title_fullStr | Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} |
title_full_unstemmed | Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} |
title_short | Bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(II)} |
title_sort | bis[μ-2-(2-naphthoxy)acetato]bis{aqua[2-(2-naphthoxy)acetato]zinc(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977591/ https://www.ncbi.nlm.nih.gov/pubmed/21583777 http://dx.doi.org/10.1107/S1600536809013750 |
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