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Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}

The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphth­oxy­acetate anion and one water mol­ecule in a distorted ZnO(4) tetra­hedral geometry. The naphthalene system of...

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Detalles Bibliográficos
Autores principales: Chen, Fang-Jun, Xu, Hai, Xu, Hui, Huang, Ke-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977591/
https://www.ncbi.nlm.nih.gov/pubmed/21583777
http://dx.doi.org/10.1107/S1600536809013750
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author Chen, Fang-Jun
Xu, Hai
Xu, Hui
Huang, Ke-Long
author_facet Chen, Fang-Jun
Xu, Hai
Xu, Hui
Huang, Ke-Long
author_sort Chen, Fang-Jun
collection PubMed
description The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphth­oxy­acetate anion and one water mol­ecule in a distorted ZnO(4) tetra­hedral geometry. The naphthalene system of the bridging ligand is nearly perpendicular to the naphthalene of the terminal ligand, with a dihedral angle of 78.26 (6)°. Within the binuclear mol­ecule the Zn⋯Zn separation is 3.815 (5) Å. In the crystal structure, inter­molecular O—H⋯O hydrogen bonding between the water mol­ecule and carboxyl­ate groups helps to stabilize the crystal structure.
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spelling pubmed-29775912010-12-30 Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)} Chen, Fang-Jun Xu, Hai Xu, Hui Huang, Ke-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphth­oxy­acetate anion and one water mol­ecule in a distorted ZnO(4) tetra­hedral geometry. The naphthalene system of the bridging ligand is nearly perpendicular to the naphthalene of the terminal ligand, with a dihedral angle of 78.26 (6)°. Within the binuclear mol­ecule the Zn⋯Zn separation is 3.815 (5) Å. In the crystal structure, inter­molecular O—H⋯O hydrogen bonding between the water mol­ecule and carboxyl­ate groups helps to stabilize the crystal structure. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977591/ /pubmed/21583777 http://dx.doi.org/10.1107/S1600536809013750 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Fang-Jun
Xu, Hai
Xu, Hui
Huang, Ke-Long
Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}
title Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}
title_full Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}
title_fullStr Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}
title_full_unstemmed Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}
title_short Bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(II)}
title_sort bis[μ-2-(2-naphth­oxy)acetato]bis­{aqua[2-(2-naphth­oxy)acetato]zinc(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977591/
https://www.ncbi.nlm.nih.gov/pubmed/21583777
http://dx.doi.org/10.1107/S1600536809013750
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