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Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) O,N′]cadmium(II) dimethyl sulfoxide disolvate
The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O′-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of s...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977592/ https://www.ncbi.nlm.nih.gov/pubmed/21583778 http://dx.doi.org/10.1107/S1600536809013774 |
| Sumario: | The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O′-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the –NH– unit, and O—H⋯O hydrogen bonds link molecules into a supramolecular chain. |
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