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Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) O,N′]cadmium(II) dimethyl sulfoxide disolvate
The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O′-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of s...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977592/ https://www.ncbi.nlm.nih.gov/pubmed/21583778 http://dx.doi.org/10.1107/S1600536809013774 |
| _version_ | 1782191141297324032 |
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| author | Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng |
| author_facet | Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng |
| author_sort | Mohd Lair, Nooraziah |
| collection | PubMed |
| description | The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O′-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the –NH– unit, and O—H⋯O hydrogen bonds link molecules into a supramolecular chain. |
| format | Text |
| id | pubmed-2977592 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775922010-12-30 Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) O,N′]cadmium(II) dimethyl sulfoxide disolvate Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O′-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the –NH– unit, and O—H⋯O hydrogen bonds link molecules into a supramolecular chain. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977592/ /pubmed/21583778 http://dx.doi.org/10.1107/S1600536809013774 Text en © Mohd Lair et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) O,N′]cadmium(II) dimethyl sulfoxide disolvate |
| title | Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
O,N′]cadmium(II) dimethyl sulfoxide disolvate |
| title_full | Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
O,N′]cadmium(II) dimethyl sulfoxide disolvate |
| title_fullStr | Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
O,N′]cadmium(II) dimethyl sulfoxide disolvate |
| title_full_unstemmed | Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
O,N′]cadmium(II) dimethyl sulfoxide disolvate |
| title_short | Bis[4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
O,N′]cadmium(II) dimethyl sulfoxide disolvate |
| title_sort | bis[4-hydroxy-n′-(4-methoxy-2-oxidobenzylidene-κo
(2))benzohydrazidato-κ(2)
o,n′]cadmium(ii) dimethyl sulfoxide disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977592/ https://www.ncbi.nlm.nih.gov/pubmed/21583778 http://dx.doi.org/10.1107/S1600536809013774 |
| work_keys_str_mv | AT mohdlairnooraziah bis4hydroxyn4methoxy2oxidobenzylideneko2benzohydrazidatok2oncadmiumiidimethylsulfoxidedisolvate AT mohdalihapipah bis4hydroxyn4methoxy2oxidobenzylideneko2benzohydrazidatok2oncadmiumiidimethylsulfoxidedisolvate AT ngseikweng bis4hydroxyn4methoxy2oxidobenzylideneko2benzohydrazidatok2oncadmiumiidimethylsulfoxidedisolvate |