trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)

In the title complex, [Zn(C(4)H(3)N(6))(2)(H(2)O)(2)], the metal centre lies on an inversion centre and displays a distorted octa­hedral ZnN(4)O(2) coordination geometry. The organic ligand is not planar; the dihedral angle between the imidazole and tetra­zole rings is 8.39 (9)°. An extended network...

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Detalles Bibliográficos
Autores principales: Zhao, Hong, Xiao, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977593/
https://www.ncbi.nlm.nih.gov/pubmed/21583779
http://dx.doi.org/10.1107/S1600536809013567
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author Zhao, Hong
Xiao, Jie
author_facet Zhao, Hong
Xiao, Jie
author_sort Zhao, Hong
collection PubMed
description In the title complex, [Zn(C(4)H(3)N(6))(2)(H(2)O)(2)], the metal centre lies on an inversion centre and displays a distorted octa­hedral ZnN(4)O(2) coordination geometry. The organic ligand is not planar; the dihedral angle between the imidazole and tetra­zole rings is 8.39 (9)°. An extended network of inter­molecular N—H⋯N and O—H⋯N hydrogen bonds stabilizes the crystal structure.
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spelling pubmed-29775932010-12-30 trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II) Zhao, Hong Xiao, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(4)H(3)N(6))(2)(H(2)O)(2)], the metal centre lies on an inversion centre and displays a distorted octa­hedral ZnN(4)O(2) coordination geometry. The organic ligand is not planar; the dihedral angle between the imidazole and tetra­zole rings is 8.39 (9)°. An extended network of inter­molecular N—H⋯N and O—H⋯N hydrogen bonds stabilizes the crystal structure. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977593/ /pubmed/21583779 http://dx.doi.org/10.1107/S1600536809013567 Text en © Zhao and Xiao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Hong
Xiao, Jie
trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)
title trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)
title_full trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)
title_fullStr trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)
title_full_unstemmed trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)
title_short trans-Diaqua­bis[5-(1H-imidazol-4-yl-κN (3))-1H-tetra­zolato-κN (1)]zinc(II)
title_sort trans-diaqua­bis[5-(1h-imidazol-4-yl-κn (3))-1h-tetra­zolato-κn (1)]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977593/
https://www.ncbi.nlm.nih.gov/pubmed/21583779
http://dx.doi.org/10.1107/S1600536809013567
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AT xiaojie transdiaquabis51himidazol4ylkn31htetrazolatokn1zincii

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