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Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)

In the monomeric and centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-chloro­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinating water mol­ecule,...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Özbek, F. Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977595/
https://www.ncbi.nlm.nih.gov/pubmed/21583781
http://dx.doi.org/10.1107/S1600536809014226
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the monomeric and centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-chloro­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinating water mol­ecule, the ligands being monodentate. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two N atoms of the DENA ligands in axial positions. The dihedral angle between the benzene ring and the attached carboxyl­ate group is 87.36 (10)°, while the pyridine and benzene rings are oriented at an angle of 41.90 (5)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (10[Image: see text]).
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spelling pubmed-29775952010-12-30 Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric and centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-chloro­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinating water mol­ecule, the ligands being monodentate. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two N atoms of the DENA ligands in axial positions. The dihedral angle between the benzene ring and the attached carboxyl­ate group is 87.36 (10)°, while the pyridine and benzene rings are oriented at an angle of 41.90 (5)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (10[Image: see text]). International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977595/ /pubmed/21583781 http://dx.doi.org/10.1107/S1600536809014226 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_full Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_fullStr Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_full_unstemmed Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_short Diaqua­bis(2-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_sort diaqua­bis(2-chloro­benzoato-κo)bis­(n,n-diethyl­nicotinamide-κn (1))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977595/
https://www.ncbi.nlm.nih.gov/pubmed/21583781
http://dx.doi.org/10.1107/S1600536809014226
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