Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)

In the title complex, [Mn(C(4)N(3))(2)(C(10)H(8)N(2)O(2))(2)], the Mn(II) atom lies on an inversion center and is coordinated by two 2,2′-bipyridine N,N′-dioxide (dpdo) mol­ecules and two tricyano­methanide (tcm) ligands to form a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O or C—H⋯N h...

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Detalles Bibliográficos
Autores principales: Luo, Jun, Yang, Feng, Qiu, Li-Juan, Wang, Xin-Xia, Liu, Bao-Shu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977596/
https://www.ncbi.nlm.nih.gov/pubmed/21583782
http://dx.doi.org/10.1107/S1600536809013828
Descripción
Sumario:In the title complex, [Mn(C(4)N(3))(2)(C(10)H(8)N(2)O(2))(2)], the Mn(II) atom lies on an inversion center and is coordinated by two 2,2′-bipyridine N,N′-dioxide (dpdo) mol­ecules and two tricyano­methanide (tcm) ligands to form a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O or C—H⋯N hydrogen bonds, involving either the O atom of the dpdo mol­ecule and the pyridyl H atom, or the N atom of the tcm anion and the pyridyl H atom, result in the formation of a three-dimensional network structure.

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