Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)

In the title complex, [Mn(C(4)N(3))(2)(C(10)H(8)N(2)O(2))(2)], the Mn(II) atom lies on an inversion center and is coordinated by two 2,2′-bipyridine N,N′-dioxide (dpdo) mol­ecules and two tricyano­methanide (tcm) ligands to form a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O or C—H⋯N h...

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Detalles Bibliográficos
Autores principales: Luo, Jun, Yang, Feng, Qiu, Li-Juan, Wang, Xin-Xia, Liu, Bao-Shu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977596/
https://www.ncbi.nlm.nih.gov/pubmed/21583782
http://dx.doi.org/10.1107/S1600536809013828
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author Luo, Jun
Yang, Feng
Qiu, Li-Juan
Wang, Xin-Xia
Liu, Bao-Shu
author_facet Luo, Jun
Yang, Feng
Qiu, Li-Juan
Wang, Xin-Xia
Liu, Bao-Shu
author_sort Luo, Jun
collection PubMed
description In the title complex, [Mn(C(4)N(3))(2)(C(10)H(8)N(2)O(2))(2)], the Mn(II) atom lies on an inversion center and is coordinated by two 2,2′-bipyridine N,N′-dioxide (dpdo) mol­ecules and two tricyano­methanide (tcm) ligands to form a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O or C—H⋯N hydrogen bonds, involving either the O atom of the dpdo mol­ecule and the pyridyl H atom, or the N atom of the tcm anion and the pyridyl H atom, result in the formation of a three-dimensional network structure.
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spelling pubmed-29775962010-12-30 Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II) Luo, Jun Yang, Feng Qiu, Li-Juan Wang, Xin-Xia Liu, Bao-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(4)N(3))(2)(C(10)H(8)N(2)O(2))(2)], the Mn(II) atom lies on an inversion center and is coordinated by two 2,2′-bipyridine N,N′-dioxide (dpdo) mol­ecules and two tricyano­methanide (tcm) ligands to form a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O or C—H⋯N hydrogen bonds, involving either the O atom of the dpdo mol­ecule and the pyridyl H atom, or the N atom of the tcm anion and the pyridyl H atom, result in the formation of a three-dimensional network structure. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977596/ /pubmed/21583782 http://dx.doi.org/10.1107/S1600536809013828 Text en © Luo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Jun
Yang, Feng
Qiu, Li-Juan
Wang, Xin-Xia
Liu, Bao-Shu
Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)
title Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)
title_full Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)
title_fullStr Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)
title_full_unstemmed Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)
title_short Bis(2,2′-bipyridine N,N′-dioxide)bis­(tri­cyano­methanido)manganese(II)
title_sort bis(2,2′-bipyridine n,n′-dioxide)bis­(tri­cyano­methanido)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977596/
https://www.ncbi.nlm.nih.gov/pubmed/21583782
http://dx.doi.org/10.1107/S1600536809013828
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AT qiulijuan bis22bipyridinenndioxidebistricyanomethanidomanganeseii
AT wangxinxia bis22bipyridinenndioxidebistricyanomethanidomanganeseii
AT liubaoshu bis22bipyridinenndioxidebistricyanomethanidomanganeseii

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