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Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4) O (2),N (1),S:O (2);κ(4) O (2):O (2),N (1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate
The two Zn(II) atoms in the title compound, [Zn(2)(C(10)H(12)N(3)O(2)S)(2)Cl(2)]·3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn(2)O(2) core. Each Zn atom has a Cl atom in the apical positi...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977597/ https://www.ncbi.nlm.nih.gov/pubmed/21583783 http://dx.doi.org/10.1107/S1600536809013385 |
| _version_ | 1782191142479069184 |
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| author | Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng |
| author_facet | Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng |
| author_sort | Tan, Kong Wai |
| collection | PubMed |
| description | The two Zn(II) atoms in the title compound, [Zn(2)(C(10)H(12)N(3)O(2)S)(2)Cl(2)]·3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn(2)O(2) core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy–DMSO (DMSO is dimethyl sulfoxide) O—H⋯O and amide–DMSO N—H⋯O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight. |
| format | Text |
| id | pubmed-2977597 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775972010-12-30 Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4) O (2),N (1),S:O (2);κ(4) O (2):O (2),N (1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two Zn(II) atoms in the title compound, [Zn(2)(C(10)H(12)N(3)O(2)S)(2)Cl(2)]·3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn(2)O(2) core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy–DMSO (DMSO is dimethyl sulfoxide) O—H⋯O and amide–DMSO N—H⋯O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977597/ /pubmed/21583783 http://dx.doi.org/10.1107/S1600536809013385 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4) O (2),N (1),S:O (2);κ(4) O (2):O (2),N (1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate |
| title | Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4)
O
(2),N
(1),S:O
(2);κ(4)
O
(2):O
(2),N
(1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate |
| title_full | Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4)
O
(2),N
(1),S:O
(2);κ(4)
O
(2):O
(2),N
(1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate |
| title_fullStr | Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4)
O
(2),N
(1),S:O
(2);κ(4)
O
(2):O
(2),N
(1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate |
| title_full_unstemmed | Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4)
O
(2),N
(1),S:O
(2);κ(4)
O
(2):O
(2),N
(1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate |
| title_short | Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4)
O
(2),N
(1),S:O
(2);κ(4)
O
(2):O
(2),N
(1),S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate |
| title_sort | bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ(4)
o
(2),n
(1),s:o
(2);κ(4)
o
(2):o
(2),n
(1),s-bis[chloridozinc(ii)] dimethyl sulfoxide trisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977597/ https://www.ncbi.nlm.nih.gov/pubmed/21583783 http://dx.doi.org/10.1107/S1600536809013385 |
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