Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate

The title complex, [Cu(3)(C(9)H(8)BrNO(4)S)(2)(C(7)H(4)BrO(2))(2)(C(10)H(8)N(2))(2)]·H(2)O, lies on an inversion center located on the central Cu atom, which is four-coordinated in a square-planar geometry, whereas the outer Cu atoms related by symmetry are five-coordinated in a square-pyramidal geo...

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Detalles Bibliográficos
Autor principal: Zhang, Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977599/
https://www.ncbi.nlm.nih.gov/pubmed/21583785
http://dx.doi.org/10.1107/S1600536809014263
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author Zhang, Ling
author_facet Zhang, Ling
author_sort Zhang, Ling
collection PubMed
description The title complex, [Cu(3)(C(9)H(8)BrNO(4)S)(2)(C(7)H(4)BrO(2))(2)(C(10)H(8)N(2))(2)]·H(2)O, lies on an inversion center located on the central Cu atom, which is four-coordinated in a square-planar geometry, whereas the outer Cu atoms related by symmetry are five-coordinated in a square-pyramidal geometry. The trinuclear mol­ecules, with an intramolecular Cu⋯Cu separation of 6.313 (3) Å, are linked to each other, forming a chain through O—H⋯O and O—H⋯Br hydrogen bonds involving the half-occupied water mol­ecule. Futhermore, weak C—H⋯O inter­actions link the chains to form a supra­molecular network.
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spelling pubmed-29775992010-12-30 Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate Zhang, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(3)(C(9)H(8)BrNO(4)S)(2)(C(7)H(4)BrO(2))(2)(C(10)H(8)N(2))(2)]·H(2)O, lies on an inversion center located on the central Cu atom, which is four-coordinated in a square-planar geometry, whereas the outer Cu atoms related by symmetry are five-coordinated in a square-pyramidal geometry. The trinuclear mol­ecules, with an intramolecular Cu⋯Cu separation of 6.313 (3) Å, are linked to each other, forming a chain through O—H⋯O and O—H⋯Br hydrogen bonds involving the half-occupied water mol­ecule. Futhermore, weak C—H⋯O inter­actions link the chains to form a supra­molecular network. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977599/ /pubmed/21583785 http://dx.doi.org/10.1107/S1600536809014263 Text en © Ling Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Ling
Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate
title Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate
title_full Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate
title_fullStr Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate
title_full_unstemmed Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate
title_short Bis(2,2′-bipyrid­yl)-1κ(2) N,N′;3κ(2) N,N′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) O,O′;3κ(2) O,O′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) O:N,O (2);2:3κ(3) N,O (2):O-tricopper(II) monohydrate
title_sort bis(2,2′-bipyrid­yl)-1κ(2) n,n′;3κ(2) n,n′-bis­(4-bromo-2-formyl­phenolato)-1κ(2) o,o′;3κ(2) o,o′-bis­[μ-2-(5-bromo-2-oxidobenzylidene­amino)­ethane­sul­fon­ato]-1:2κ(3) o:n,o (2);2:3κ(3) n,o (2):o-tricopper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977599/
https://www.ncbi.nlm.nih.gov/pubmed/21583785
http://dx.doi.org/10.1107/S1600536809014263
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