Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)

The Cu(II) atom in the title complex, [CuCl(2)(C(12)H(9)IN(2))], has a square-planar coordination being N,N′-chelated by the Schiff base ligand, and by two Cl atoms. The geometry is distorted towards square pyramidal owing to a long Cu⋯Cl inter­action of 2.941 (1) Å. This results in the formation of...

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Detalles Bibliográficos
Autores principales: Mahmoudi, Ali, Khalaj, Mehdi, Gao, Shan, Ng, Seik Weng, Mohammadgholiha, Mahmoud
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977602/
https://www.ncbi.nlm.nih.gov/pubmed/21583788
http://dx.doi.org/10.1107/S1600536809011684
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author Mahmoudi, Ali
Khalaj, Mehdi
Gao, Shan
Ng, Seik Weng
Mohammadgholiha, Mahmoud
author_facet Mahmoudi, Ali
Khalaj, Mehdi
Gao, Shan
Ng, Seik Weng
Mohammadgholiha, Mahmoud
author_sort Mahmoudi, Ali
collection PubMed
description The Cu(II) atom in the title complex, [CuCl(2)(C(12)H(9)IN(2))], has a square-planar coordination being N,N′-chelated by the Schiff base ligand, and by two Cl atoms. The geometry is distorted towards square pyramidal owing to a long Cu⋯Cl inter­action of 2.941 (1) Å. This results in the formation of a zigzag chain structure propagating in the c-axis direction.
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spelling pubmed-29776022010-12-30 Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II) Mahmoudi, Ali Khalaj, Mehdi Gao, Shan Ng, Seik Weng Mohammadgholiha, Mahmoud Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title complex, [CuCl(2)(C(12)H(9)IN(2))], has a square-planar coordination being N,N′-chelated by the Schiff base ligand, and by two Cl atoms. The geometry is distorted towards square pyramidal owing to a long Cu⋯Cl inter­action of 2.941 (1) Å. This results in the formation of a zigzag chain structure propagating in the c-axis direction. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977602/ /pubmed/21583788 http://dx.doi.org/10.1107/S1600536809011684 Text en © Mahmoudi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mahmoudi, Ali
Khalaj, Mehdi
Gao, Shan
Ng, Seik Weng
Mohammadgholiha, Mahmoud
Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_full Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_fullStr Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_full_unstemmed Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_short Dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_sort dichlorido{2-[(4-iodo­phen­yl)imino­meth­yl]pyridine-κ(2) n,n′}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977602/
https://www.ncbi.nlm.nih.gov/pubmed/21583788
http://dx.doi.org/10.1107/S1600536809011684
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