Cargando…
Poly[diaqua(μ(3)-pyridine-3,5-dicarboxylato-κ(3) N:O (3):O (5))copper(II)]
The title complex, [Cu(C(7)H(3)NO(4))(H(2)O)(2)](n), was prepared under hydrothermal reaction conditions. In the crystal structure, the Cu(II) cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anio...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977603/ https://www.ncbi.nlm.nih.gov/pubmed/21583789 http://dx.doi.org/10.1107/S1600536809013889 |
Sumario: | The title complex, [Cu(C(7)H(3)NO(4))(H(2)O)(2)](n), was prepared under hydrothermal reaction conditions. In the crystal structure, the Cu(II) cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water molecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the Cu(II) cations to form a two-dimensional polymeric layer. O—H⋯O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supramolecular framework. |
---|