Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]

The title complex, [Cu(C(7)H(3)NO(4))(H(2)O)(2)](n), was prepared under hydro­thermal reaction conditions. In the crystal structure, the Cu(II) cation is located on a twofold rotation axis and is coordinated by two carboxyl­ate O atoms and one N atom from three pyridine-3,5-dicarboxyl­ate (PDA) anio...

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Detalles Bibliográficos
Autores principales: Du, Lin, Li, Li-Nan, Zhao, Qi-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977603/
https://www.ncbi.nlm.nih.gov/pubmed/21583789
http://dx.doi.org/10.1107/S1600536809013889
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author Du, Lin
Li, Li-Nan
Zhao, Qi-Hua
author_facet Du, Lin
Li, Li-Nan
Zhao, Qi-Hua
author_sort Du, Lin
collection PubMed
description The title complex, [Cu(C(7)H(3)NO(4))(H(2)O)(2)](n), was prepared under hydro­thermal reaction conditions. In the crystal structure, the Cu(II) cation is located on a twofold rotation axis and is coordinated by two carboxyl­ate O atoms and one N atom from three pyridine-3,5-dicarboxyl­ate (PDA) anions and two water mol­ecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the Cu(II) cations to form a two-dimensional polymeric layer. O—H⋯O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supra­molecular framework.
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spelling pubmed-29776032010-12-30 Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)] Du, Lin Li, Li-Nan Zhao, Qi-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(7)H(3)NO(4))(H(2)O)(2)](n), was prepared under hydro­thermal reaction conditions. In the crystal structure, the Cu(II) cation is located on a twofold rotation axis and is coordinated by two carboxyl­ate O atoms and one N atom from three pyridine-3,5-dicarboxyl­ate (PDA) anions and two water mol­ecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the Cu(II) cations to form a two-dimensional polymeric layer. O—H⋯O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supra­molecular framework. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977603/ /pubmed/21583789 http://dx.doi.org/10.1107/S1600536809013889 Text en © Du et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Du, Lin
Li, Li-Nan
Zhao, Qi-Hua
Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]
title Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]
title_full Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]
title_fullStr Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]
title_full_unstemmed Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]
title_short Poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) N:O (3):O (5))copper(II)]
title_sort poly[diaqua­(μ(3)-pyridine-3,5-dicarboxyl­ato-κ(3) n:o (3):o (5))copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977603/
https://www.ncbi.nlm.nih.gov/pubmed/21583789
http://dx.doi.org/10.1107/S1600536809013889
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