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Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum
Reaction of the tricarbonyl{η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum anion and dichloridodiphenylstannane affords the title compound, [MoSn(C(6)H(5))(2)Cl(C(9)H(14)N)(CO)(3)], which exhibits a four-legged piano-stool geometry with chloridodiphenylstannyl ligands unperturbed...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977605/ https://www.ncbi.nlm.nih.gov/pubmed/21583791 http://dx.doi.org/10.1107/S1600536809014329 |
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| author | Fischer, Paul J. Krohn, Kristina M. Young Jr, Victor G. |
| author_facet | Fischer, Paul J. Krohn, Kristina M. Young Jr, Victor G. |
| author_sort | Fischer, Paul J. |
| collection | PubMed |
| description | Reaction of the tricarbonyl{η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum anion and dichloridodiphenylstannane affords the title compound, [MoSn(C(6)H(5))(2)Cl(C(9)H(14)N)(CO)(3)], which exhibits a four-legged piano-stool geometry with chloridodiphenylstannyl ligands unperturbed by the pendant 2-(dimethylamino)ethyl groups. The Mo—Sn bond length [2.7584 (5) Å] and the distortion of the tetrahedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonylmolybdenum and -tungsten complexes. |
| format | Text |
| id | pubmed-2977605 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29776052010-12-30 Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum Fischer, Paul J. Krohn, Kristina M. Young Jr, Victor G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Reaction of the tricarbonyl{η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum anion and dichloridodiphenylstannane affords the title compound, [MoSn(C(6)H(5))(2)Cl(C(9)H(14)N)(CO)(3)], which exhibits a four-legged piano-stool geometry with chloridodiphenylstannyl ligands unperturbed by the pendant 2-(dimethylamino)ethyl groups. The Mo—Sn bond length [2.7584 (5) Å] and the distortion of the tetrahedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonylmolybdenum and -tungsten complexes. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977605/ /pubmed/21583791 http://dx.doi.org/10.1107/S1600536809014329 Text en © Fischer et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fischer, Paul J. Krohn, Kristina M. Young Jr, Victor G. Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| title | Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| title_full | Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| title_fullStr | Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| title_full_unstemmed | Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| title_short | Tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| title_sort | tricarbonyl(chlorodiphenylstannyl){η(5)-[2-(dimethylamino)ethyl]cyclopentadienyl}molybdenum |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977605/ https://www.ncbi.nlm.nih.gov/pubmed/21583791 http://dx.doi.org/10.1107/S1600536809014329 |
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