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Piperazinediium tetrachloridozincate(II)
In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetrahedral geometry. In the crystal, the dication and dianion interact by way of N—H⋯Cl and N—H⋯(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unba...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977610/ https://www.ncbi.nlm.nih.gov/pubmed/21583796 http://dx.doi.org/10.1107/S1600536809013981 |
| _version_ | 1782191145740140544 |
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| author | Sutherland, Pamela A. Harrison, William T. A. |
| author_facet | Sutherland, Pamela A. Harrison, William T. A. |
| author_sort | Sutherland, Pamela A. |
| collection | PubMed |
| description | In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetrahedral geometry. In the crystal, the dication and dianion interact by way of N—H⋯Cl and N—H⋯(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unbalanced, with three Cl atoms accepting two hydrogen bonds each and one Cl atom not accepting any hydrogen bonds: the latter shows the shortest Zn—Cl bond length. The crystal studied was found to be an inversion twin. |
| format | Text |
| id | pubmed-2977610 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29776102010-12-30 Piperazinediium tetrachloridozincate(II) Sutherland, Pamela A. Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetrahedral geometry. In the crystal, the dication and dianion interact by way of N—H⋯Cl and N—H⋯(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unbalanced, with three Cl atoms accepting two hydrogen bonds each and one Cl atom not accepting any hydrogen bonds: the latter shows the shortest Zn—Cl bond length. The crystal studied was found to be an inversion twin. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977610/ /pubmed/21583796 http://dx.doi.org/10.1107/S1600536809013981 Text en © Sutherland and Harrison 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sutherland, Pamela A. Harrison, William T. A. Piperazinediium tetrachloridozincate(II) |
| title | Piperazinediium tetrachloridozincate(II) |
| title_full | Piperazinediium tetrachloridozincate(II) |
| title_fullStr | Piperazinediium tetrachloridozincate(II) |
| title_full_unstemmed | Piperazinediium tetrachloridozincate(II) |
| title_short | Piperazinediium tetrachloridozincate(II) |
| title_sort | piperazinediium tetrachloridozincate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977610/ https://www.ncbi.nlm.nih.gov/pubmed/21583796 http://dx.doi.org/10.1107/S1600536809013981 |
| work_keys_str_mv | AT sutherlandpamelaa piperazinediiumtetrachloridozincateii AT harrisonwilliamta piperazinediiumtetrachloridozincateii |