Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)

In the crystal structure of the title compound, [Ni(C(14)H(13)N(2)O)(2)], the Ni(II) ion is located on an inversion center and is coordinated by two 4-methyl-2-(4-methyl­phenyl­diazen­yl)phenolate anions in a slightly distorted square-planar geometry. Within the anion, the two benzene rings are twis...

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Detalles Bibliográficos
Autores principales: Guan, Dexin, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977611/
https://www.ncbi.nlm.nih.gov/pubmed/21583797
http://dx.doi.org/10.1107/S1600536809013920
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author Guan, Dexin
Sun, Hongjian
author_facet Guan, Dexin
Sun, Hongjian
author_sort Guan, Dexin
collection PubMed
description In the crystal structure of the title compound, [Ni(C(14)H(13)N(2)O)(2)], the Ni(II) ion is located on an inversion center and is coordinated by two 4-methyl-2-(4-methyl­phenyl­diazen­yl)phenolate anions in a slightly distorted square-planar geometry. Within the anion, the two benzene rings are twisted from each other with a dihedral angle of 45.97 (12)°. No hydrogen bonding is found in the crystal structure.
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spelling pubmed-29776112010-12-30 Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II) Guan, Dexin Sun, Hongjian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ni(C(14)H(13)N(2)O)(2)], the Ni(II) ion is located on an inversion center and is coordinated by two 4-methyl-2-(4-methyl­phenyl­diazen­yl)phenolate anions in a slightly distorted square-planar geometry. Within the anion, the two benzene rings are twisted from each other with a dihedral angle of 45.97 (12)°. No hydrogen bonding is found in the crystal structure. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977611/ /pubmed/21583797 http://dx.doi.org/10.1107/S1600536809013920 Text en © Guan and Sun 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guan, Dexin
Sun, Hongjian
Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)
title Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)
title_full Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)
title_fullStr Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)
title_full_unstemmed Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)
title_short Bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) N,O]nickel(II)
title_sort bis[4-methyl-2-(4-methyl­phenyldiazen­yl)phenolato-κ(2) n,o]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977611/
https://www.ncbi.nlm.nih.gov/pubmed/21583797
http://dx.doi.org/10.1107/S1600536809013920
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