Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]

In the crystal structure of the title complex, [Zn(2)Cl(4)(C(12)H(8)N(2))(2)], each of the two five-coordinated Zn(II) atoms displays a strongly distorted trigonal-bipyramidal geometry defined by two N atoms from the chelate ligand and by one terminal and two bridging chloride anions. The crystal st...

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Detalles Bibliográficos
Autores principales: Yang, Xiao-Mao, Leng, Qing-Bo, Chen, Yi, He, You-Gang, Luo, Shi-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977612/
https://www.ncbi.nlm.nih.gov/pubmed/21583798
http://dx.doi.org/10.1107/S1600536809014482
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author Yang, Xiao-Mao
Leng, Qing-Bo
Chen, Yi
He, You-Gang
Luo, Shi-Wu
author_facet Yang, Xiao-Mao
Leng, Qing-Bo
Chen, Yi
He, You-Gang
Luo, Shi-Wu
author_sort Yang, Xiao-Mao
collection PubMed
description In the crystal structure of the title complex, [Zn(2)Cl(4)(C(12)H(8)N(2))(2)], each of the two five-coordinated Zn(II) atoms displays a strongly distorted trigonal-bipyramidal geometry defined by two N atoms from the chelate ligand and by one terminal and two bridging chloride anions. The crystal structure is stabilized by C—H⋯Cl inter­actions. There is inter­molecular π–π stacking between adjacent phenanthroline ligands, with a centroid–centroid distance of 3.151 (3) Å.
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spelling pubmed-29776122010-12-30 Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)] Yang, Xiao-Mao Leng, Qing-Bo Chen, Yi He, You-Gang Luo, Shi-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Zn(2)Cl(4)(C(12)H(8)N(2))(2)], each of the two five-coordinated Zn(II) atoms displays a strongly distorted trigonal-bipyramidal geometry defined by two N atoms from the chelate ligand and by one terminal and two bridging chloride anions. The crystal structure is stabilized by C—H⋯Cl inter­actions. There is inter­molecular π–π stacking between adjacent phenanthroline ligands, with a centroid–centroid distance of 3.151 (3) Å. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977612/ /pubmed/21583798 http://dx.doi.org/10.1107/S1600536809014482 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Xiao-Mao
Leng, Qing-Bo
Chen, Yi
He, You-Gang
Luo, Shi-Wu
Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
title Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
title_full Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
title_fullStr Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
title_full_unstemmed Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
title_short Di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
title_sort di-μ-chlorido-bis­[chlorido(1,10-phenanthroline-κ(2) n,n′)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977612/
https://www.ncbi.nlm.nih.gov/pubmed/21583798
http://dx.doi.org/10.1107/S1600536809014482
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