[2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)

In the title compound, [MnCl(2)(C(11)H(13)N(5))], the Mn(II) ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion...

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Detalles Bibliográficos
Autores principales: Ren, Chun-Xia, Li, Su-Yun, Yin, Zhao-Zhong, Lu, Xiang, Ding, Yu-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977615/
https://www.ncbi.nlm.nih.gov/pubmed/21583801
http://dx.doi.org/10.1107/S1600536809014354
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author Ren, Chun-Xia
Li, Su-Yun
Yin, Zhao-Zhong
Lu, Xiang
Ding, Yu-Qiang
author_facet Ren, Chun-Xia
Li, Su-Yun
Yin, Zhao-Zhong
Lu, Xiang
Ding, Yu-Qiang
author_sort Ren, Chun-Xia
collection PubMed
description In the title compound, [MnCl(2)(C(11)H(13)N(5))], the Mn(II) ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position. Both dihydro­imidazole rings adopt envelope conformations. In the crystal structure, mol­ecules are linked into a three-dimensional network by N—H⋯Cl and C—H⋯Cl hydrogen bonds.
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spelling pubmed-29776152010-12-30 [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II) Ren, Chun-Xia Li, Su-Yun Yin, Zhao-Zhong Lu, Xiang Ding, Yu-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MnCl(2)(C(11)H(13)N(5))], the Mn(II) ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis­(4,5-dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position. Both dihydro­imidazole rings adopt envelope conformations. In the crystal structure, mol­ecules are linked into a three-dimensional network by N—H⋯Cl and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977615/ /pubmed/21583801 http://dx.doi.org/10.1107/S1600536809014354 Text en © Ren et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ren, Chun-Xia
Li, Su-Yun
Yin, Zhao-Zhong
Lu, Xiang
Ding, Yu-Qiang
[2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
title [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
title_full [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
title_fullStr [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
title_full_unstemmed [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
title_short [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
title_sort [2,6-bis(4,5-dihydro-1h-imidazol-2-yl)pyridine]dichloridomanganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977615/
https://www.ncbi.nlm.nih.gov/pubmed/21583801
http://dx.doi.org/10.1107/S1600536809014354
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AT lisuyun 26bis45dihydro1himidazol2ylpyridinedichloridomanganeseii
AT yinzhaozhong 26bis45dihydro1himidazol2ylpyridinedichloridomanganeseii
AT luxiang 26bis45dihydro1himidazol2ylpyridinedichloridomanganeseii
AT dingyuqiang 26bis45dihydro1himidazol2ylpyridinedichloridomanganeseii

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