Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)

The title compound, [Zn(C(8)H(4)O(4))(C(5)H(8)N(2))(3)], has a neutral monomeric structure in which one terephthalate dianion and three 2-ethyl-1H-imidazole ligands coordinate to the Zn(II) ion in a distorted tetra­hedral geometry. The methyl group of one of the ethyl groups is disordered over two p...

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Detalles Bibliográficos
Autores principales: Xie, Quan-An, Dong, Gui-Ying, Yu, Ya-Mei, Wang, Yong-Gang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977618/
https://www.ncbi.nlm.nih.gov/pubmed/21583804
http://dx.doi.org/10.1107/S1600536809014755
Descripción
Sumario:The title compound, [Zn(C(8)H(4)O(4))(C(5)H(8)N(2))(3)], has a neutral monomeric structure in which one terephthalate dianion and three 2-ethyl-1H-imidazole ligands coordinate to the Zn(II) ion in a distorted tetra­hedral geometry. The methyl group of one of the ethyl groups is disordered over two positions with occupancies of 0.66 (2) and 0.34 (2). In the crystal structure, mol­ecules are linked into a three-dimensional hydrogen-bonded network by inter­molecular N—H⋯O interactions involving the uncoordinated carboxyl­ate O atoms.

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