Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)

The title compound, [Zn(C(8)H(4)O(4))(C(5)H(8)N(2))(3)], has a neutral monomeric structure in which one terephthalate dianion and three 2-ethyl-1H-imidazole ligands coordinate to the Zn(II) ion in a distorted tetra­hedral geometry. The methyl group of one of the ethyl groups is disordered over two p...

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Detalles Bibliográficos
Autores principales: Xie, Quan-An, Dong, Gui-Ying, Yu, Ya-Mei, Wang, Yong-Gang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977618/
https://www.ncbi.nlm.nih.gov/pubmed/21583804
http://dx.doi.org/10.1107/S1600536809014755
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author Xie, Quan-An
Dong, Gui-Ying
Yu, Ya-Mei
Wang, Yong-Gang
author_facet Xie, Quan-An
Dong, Gui-Ying
Yu, Ya-Mei
Wang, Yong-Gang
author_sort Xie, Quan-An
collection PubMed
description The title compound, [Zn(C(8)H(4)O(4))(C(5)H(8)N(2))(3)], has a neutral monomeric structure in which one terephthalate dianion and three 2-ethyl-1H-imidazole ligands coordinate to the Zn(II) ion in a distorted tetra­hedral geometry. The methyl group of one of the ethyl groups is disordered over two positions with occupancies of 0.66 (2) and 0.34 (2). In the crystal structure, mol­ecules are linked into a three-dimensional hydrogen-bonded network by inter­molecular N—H⋯O interactions involving the uncoordinated carboxyl­ate O atoms.
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spelling pubmed-29776182010-12-30 Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II) Xie, Quan-An Dong, Gui-Ying Yu, Ya-Mei Wang, Yong-Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(8)H(4)O(4))(C(5)H(8)N(2))(3)], has a neutral monomeric structure in which one terephthalate dianion and three 2-ethyl-1H-imidazole ligands coordinate to the Zn(II) ion in a distorted tetra­hedral geometry. The methyl group of one of the ethyl groups is disordered over two positions with occupancies of 0.66 (2) and 0.34 (2). In the crystal structure, mol­ecules are linked into a three-dimensional hydrogen-bonded network by inter­molecular N—H⋯O interactions involving the uncoordinated carboxyl­ate O atoms. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977618/ /pubmed/21583804 http://dx.doi.org/10.1107/S1600536809014755 Text en © Xie et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Quan-An
Dong, Gui-Ying
Yu, Ya-Mei
Wang, Yong-Gang
Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)
title Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)
title_full Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)
title_fullStr Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)
title_full_unstemmed Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)
title_short Tris(2-ethyl-1H-imidazole-κN (3))(terephthalato-κO)zinc(II)
title_sort tris(2-ethyl-1h-imidazole-κn (3))(terephthalato-κo)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977618/
https://www.ncbi.nlm.nih.gov/pubmed/21583804
http://dx.doi.org/10.1107/S1600536809014755
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