{μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)

Each of the Al atoms in the title compound, [Al(2)(CH(3))(5)(C(15)H(15)FNO)], is four-coordinated in a distorted tetra­hedral geometry. The dimethyl­aluminium centre is bound by the N and the O atoms of the (2-dimethyl­amino­phen­yl)(2-fluoro­phen­yl)methano­late ligand. The second Al atom is bound...

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Detalles Bibliográficos
Autores principales: Gao, Aihong, Su, Qing, Mu, Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977619/
https://www.ncbi.nlm.nih.gov/pubmed/21583805
http://dx.doi.org/10.1107/S1600536809012252
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author Gao, Aihong
Su, Qing
Mu, Ying
author_facet Gao, Aihong
Su, Qing
Mu, Ying
author_sort Gao, Aihong
collection PubMed
description Each of the Al atoms in the title compound, [Al(2)(CH(3))(5)(C(15)H(15)FNO)], is four-coordinated in a distorted tetra­hedral geometry. The dimethyl­aluminium centre is bound by the N and the O atoms of the (2-dimethyl­amino­phen­yl)(2-fluoro­phen­yl)methano­late ligand. The second Al atom is bound by the methano­late O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4 (2):0.6 (2) domain ratio.
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spelling pubmed-29776192010-12-30 {μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III) Gao, Aihong Su, Qing Mu, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Each of the Al atoms in the title compound, [Al(2)(CH(3))(5)(C(15)H(15)FNO)], is four-coordinated in a distorted tetra­hedral geometry. The dimethyl­aluminium centre is bound by the N and the O atoms of the (2-dimethyl­amino­phen­yl)(2-fluoro­phen­yl)methano­late ligand. The second Al atom is bound by the methano­late O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4 (2):0.6 (2) domain ratio. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977619/ /pubmed/21583805 http://dx.doi.org/10.1107/S1600536809012252 Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Aihong
Su, Qing
Mu, Ying
{μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)
title {μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)
title_full {μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)
title_fullStr {μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)
title_full_unstemmed {μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)
title_short {μ-[2-(Dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(III)
title_sort {μ-[2-(dimethyl­amino)phen­yl](2-fluoro­phen­yl)methano­lato}penta­methyl­dialuminum(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977619/
https://www.ncbi.nlm.nih.gov/pubmed/21583805
http://dx.doi.org/10.1107/S1600536809012252
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AT suqing m2dimethylaminophenyl2fluorophenylmethanolatopentamethyldialuminumiii
AT muying m2dimethylaminophenyl2fluorophenylmethanolatopentamethyldialuminumiii

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