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Bis(2,6-dimethylpyridinium) tetrabromidozincate(II)
In the crystal structure of the title compound, (C(7)H(10)N)(2)[ZnBr(4)], the coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Zn atom. The Zn—Br bond lengths range from 2.400 (2) to 2.408 (3) Å and the Br—Zn—Br angles range from 108.14 ...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977623/ https://www.ncbi.nlm.nih.gov/pubmed/21583809 http://dx.doi.org/10.1107/S1600536809015219 |
| _version_ | 1782191148920471552 |
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| author | Ali, Basem Fares Al-Far, Rawhi |
| author_facet | Ali, Basem Fares Al-Far, Rawhi |
| author_sort | Ali, Basem Fares |
| collection | PubMed |
| description | In the crystal structure of the title compound, (C(7)H(10)N)(2)[ZnBr(4)], the coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Zn atom. The Zn—Br bond lengths range from 2.400 (2) to 2.408 (3) Å and the Br—Zn—Br angles range from 108.14 (6) to 115.15 (15)°. In the crystal structure, the [ZnBr(4)](2−) anion is connected to two cations through N—H⋯Br and H(2)C—H⋯Br hydrogen bonds, forming two-dimensional cation–anion–cation layers normal to the b axis. No significant Br⋯Br interactions [the shortest being 4.423 (4) Å] are observed in the structure. |
| format | Text |
| id | pubmed-2977623 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29776232010-12-30 Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) Ali, Basem Fares Al-Far, Rawhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(7)H(10)N)(2)[ZnBr(4)], the coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Zn atom. The Zn—Br bond lengths range from 2.400 (2) to 2.408 (3) Å and the Br—Zn—Br angles range from 108.14 (6) to 115.15 (15)°. In the crystal structure, the [ZnBr(4)](2−) anion is connected to two cations through N—H⋯Br and H(2)C—H⋯Br hydrogen bonds, forming two-dimensional cation–anion–cation layers normal to the b axis. No significant Br⋯Br interactions [the shortest being 4.423 (4) Å] are observed in the structure. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977623/ /pubmed/21583809 http://dx.doi.org/10.1107/S1600536809015219 Text en © Ali and Al-Far 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ali, Basem Fares Al-Far, Rawhi Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) |
| title | Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) |
| title_full | Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) |
| title_fullStr | Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) |
| title_full_unstemmed | Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) |
| title_short | Bis(2,6-dimethylpyridinium) tetrabromidozincate(II) |
| title_sort | bis(2,6-dimethylpyridinium) tetrabromidozincate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977623/ https://www.ncbi.nlm.nih.gov/pubmed/21583809 http://dx.doi.org/10.1107/S1600536809015219 |
| work_keys_str_mv | AT alibasemfares bis26dimethylpyridiniumtetrabromidozincateii AT alfarrawhi bis26dimethylpyridiniumtetrabromidozincateii |