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Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate

In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substanti­ally from the distorted trigonal-bipyramidal arrangement usually observed for fiv...

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Detalles Bibliográficos
Autor principal: Watton, Stephen P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977625/
https://www.ncbi.nlm.nih.gov/pubmed/21583811
http://dx.doi.org/10.1107/S1600536809012331
Descripción
Sumario:In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substanti­ally from the distorted trigonal-bipyramidal arrangement usually observed for five-coordinate complexes of Cu(II) with two phenanthroline-type ligands and one other ligand. The B atom of one of the BF(4) (−) anions is disordered over two sites in a 0.825 (2):0.175 (2) ratio. In the crystal, C—H⋯F hydrogen bonds help to establish the packing.