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Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substantially from the distorted trigonal-bipyramidal arrangement usually observed for fiv...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977625/ https://www.ncbi.nlm.nih.gov/pubmed/21583811 http://dx.doi.org/10.1107/S1600536809012331 |
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author | Watton, Stephen P. |
author_facet | Watton, Stephen P. |
author_sort | Watton, Stephen P. |
collection | PubMed |
description | In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substantially from the distorted trigonal-bipyramidal arrangement usually observed for five-coordinate complexes of Cu(II) with two phenanthroline-type ligands and one other ligand. The B atom of one of the BF(4) (−) anions is disordered over two sites in a 0.825 (2):0.175 (2) ratio. In the crystal, C—H⋯F hydrogen bonds help to establish the packing. |
format | Text |
id | pubmed-2977625 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29776252010-12-30 Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate Watton, Stephen P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substantially from the distorted trigonal-bipyramidal arrangement usually observed for five-coordinate complexes of Cu(II) with two phenanthroline-type ligands and one other ligand. The B atom of one of the BF(4) (−) anions is disordered over two sites in a 0.825 (2):0.175 (2) ratio. In the crystal, C—H⋯F hydrogen bonds help to establish the packing. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977625/ /pubmed/21583811 http://dx.doi.org/10.1107/S1600536809012331 Text en © Stephen P. Watton 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Watton, Stephen P. Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate |
title | Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate |
title_full | Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate |
title_fullStr | Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate |
title_full_unstemmed | Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate |
title_short | Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate |
title_sort | acetonitrilebis(2,9-dimethylphenanthroline)copper(ii) bis(tetrafluoridoborate) acetonitrile disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977625/ https://www.ncbi.nlm.nih.gov/pubmed/21583811 http://dx.doi.org/10.1107/S1600536809012331 |
work_keys_str_mv | AT wattonstephenp acetonitrilebis29dimethylphenanthrolinecopperiibistetrafluoridoborateacetonitriledisolvate |