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Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate

In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substanti­ally from the distorted trigonal-bipyramidal arrangement usually observed for fiv...

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Detalles Bibliográficos
Autor principal: Watton, Stephen P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977625/
https://www.ncbi.nlm.nih.gov/pubmed/21583811
http://dx.doi.org/10.1107/S1600536809012331
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author Watton, Stephen P.
author_facet Watton, Stephen P.
author_sort Watton, Stephen P.
collection PubMed
description In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substanti­ally from the distorted trigonal-bipyramidal arrangement usually observed for five-coordinate complexes of Cu(II) with two phenanthroline-type ligands and one other ligand. The B atom of one of the BF(4) (−) anions is disordered over two sites in a 0.825 (2):0.175 (2) ratio. In the crystal, C—H⋯F hydrogen bonds help to establish the packing.
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spelling pubmed-29776252010-12-30 Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate Watton, Stephen P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(CH(3)CN)(C(14)H(12)N(2))(2)](BF(4))(2)·2CH(3)CN, the Cu(II) atom shows a distorted CuN(5) square-pyramidal geometry with the acetonitrile N atom in an equatorial site, which differs substanti­ally from the distorted trigonal-bipyramidal arrangement usually observed for five-coordinate complexes of Cu(II) with two phenanthroline-type ligands and one other ligand. The B atom of one of the BF(4) (−) anions is disordered over two sites in a 0.825 (2):0.175 (2) ratio. In the crystal, C—H⋯F hydrogen bonds help to establish the packing. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977625/ /pubmed/21583811 http://dx.doi.org/10.1107/S1600536809012331 Text en © Stephen P. Watton 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Watton, Stephen P.
Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
title Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
title_full Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
title_fullStr Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
title_full_unstemmed Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
title_short Acetonitrilebis(2,9-dimethylphenanthroline)copper(II) bis(tetrafluoridoborate) acetonitrile disolvate
title_sort acetonitrilebis(2,9-dimethylphenanthroline)copper(ii) bis(tetrafluoridoborate) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977625/
https://www.ncbi.nlm.nih.gov/pubmed/21583811
http://dx.doi.org/10.1107/S1600536809012331
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