[μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate

The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N′-bis­(diphenyl­phosphinometh­yl)ben­zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin­ated by one chelating 2,2′-bipyridine l...

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Detalles Bibliográficos
Autores principales: Gui, Liu-Cheng, Ni, Qing-Ling, Jiang, Xuan-Feng, Zeng, Jian-Qiang, Wang, Xiu-Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977627/
https://www.ncbi.nlm.nih.gov/pubmed/21583813
http://dx.doi.org/10.1107/S1600536809014871
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author Gui, Liu-Cheng
Ni, Qing-Ling
Jiang, Xuan-Feng
Zeng, Jian-Qiang
Wang, Xiu-Jian
author_facet Gui, Liu-Cheng
Ni, Qing-Ling
Jiang, Xuan-Feng
Zeng, Jian-Qiang
Wang, Xiu-Jian
author_sort Gui, Liu-Cheng
collection PubMed
description The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N′-bis­(diphenyl­phosphinometh­yl)ben­zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin­ated by one chelating 2,2′-bipyridine ligand, giving a distorted trigonal coordination environment.
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spelling pubmed-29776272010-12-30 [μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate Gui, Liu-Cheng Ni, Qing-Ling Jiang, Xuan-Feng Zeng, Jian-Qiang Wang, Xiu-Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N′-bis­(diphenyl­phosphinometh­yl)ben­zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin­ated by one chelating 2,2′-bipyridine ligand, giving a distorted trigonal coordination environment. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977627/ /pubmed/21583813 http://dx.doi.org/10.1107/S1600536809014871 Text en © Gui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gui, Liu-Cheng
Ni, Qing-Ling
Jiang, Xuan-Feng
Zeng, Jian-Qiang
Wang, Xiu-Jian
[μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate
title [μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate
title_full [μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate
title_fullStr [μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate
title_full_unstemmed [μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate
title_short [μ-N,N′-Bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) P:P′]bis­[(2,2′-bipyridine-κ(2) N,N′)silver(I)] bis­(per­chlorate) acetone disolvate
title_sort [μ-n,n′-bis(diphenyl­phosphinometh­yl)benzene-1,4-diamine-κ(2) p:p′]bis­[(2,2′-bipyridine-κ(2) n,n′)silver(i)] bis­(per­chlorate) acetone disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977627/
https://www.ncbi.nlm.nih.gov/pubmed/21583813
http://dx.doi.org/10.1107/S1600536809014871
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