Diaqua­(trifluoro­acetato-κ(2) O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6)]manganese(II) trifluoro­acetate

The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N′,N′′-chelated by the neutral N-heterocycle and O,O′-chelated by the carboxyl­ate ion, the five atoms involved in chelation comprising a penta­gon around it. The apical...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977628/
https://www.ncbi.nlm.nih.gov/pubmed/21583814
http://dx.doi.org/10.1107/S1600536809015098
Descripción
Sumario:The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N′,N′′-chelated by the neutral N-heterocycle and O,O′-chelated by the carboxyl­ate ion, the five atoms involved in chelation comprising a penta­gon around it. The apical sites of the trans-penta­gonal bipyramidal coordination geometry are occupied by two water mol­ecules. The cations and lattice anions are linked by O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network.

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