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Diaqua(trifluoroacetato-κ(2) O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6)]manganese(II) trifluoroacetate
The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N′,N′′-chelated by the neutral N-heterocycle and O,O′-chelated by the carboxylate ion, the five atoms involved in chelation comprising a pentagon around it. The apical...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977628/ https://www.ncbi.nlm.nih.gov/pubmed/21583814 http://dx.doi.org/10.1107/S1600536809015098 |
| _version_ | 1782191150090682368 |
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| author | Lo, Kong Mun Ng, Seik Weng |
| author_facet | Lo, Kong Mun Ng, Seik Weng |
| author_sort | Lo, Kong Mun |
| collection | PubMed |
| description | The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N′,N′′-chelated by the neutral N-heterocycle and O,O′-chelated by the carboxylate ion, the five atoms involved in chelation comprising a pentagon around it. The apical sites of the trans-pentagonal bipyramidal coordination geometry are occupied by two water molecules. The cations and lattice anions are linked by O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. |
| format | Text |
| id | pubmed-2977628 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29776282010-12-30 Diaqua(trifluoroacetato-κ(2) O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6)]manganese(II) trifluoroacetate Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N′,N′′-chelated by the neutral N-heterocycle and O,O′-chelated by the carboxylate ion, the five atoms involved in chelation comprising a pentagon around it. The apical sites of the trans-pentagonal bipyramidal coordination geometry are occupied by two water molecules. The cations and lattice anions are linked by O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977628/ /pubmed/21583814 http://dx.doi.org/10.1107/S1600536809015098 Text en © Lo and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lo, Kong Mun Ng, Seik Weng Diaqua(trifluoroacetato-κ(2) O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6)]manganese(II) trifluoroacetate |
| title | Diaqua(trifluoroacetato-κ(2)
O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6)]manganese(II) trifluoroacetate |
| title_full | Diaqua(trifluoroacetato-κ(2)
O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6)]manganese(II) trifluoroacetate |
| title_fullStr | Diaqua(trifluoroacetato-κ(2)
O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6)]manganese(II) trifluoroacetate |
| title_full_unstemmed | Diaqua(trifluoroacetato-κ(2)
O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6)]manganese(II) trifluoroacetate |
| title_short | Diaqua(trifluoroacetato-κ(2)
O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6)]manganese(II) trifluoroacetate |
| title_sort | diaqua(trifluoroacetato-κ(2)
o,o′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
n
(2),n
(1),n
(6)]manganese(ii) trifluoroacetate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977628/ https://www.ncbi.nlm.nih.gov/pubmed/21583814 http://dx.doi.org/10.1107/S1600536809015098 |
| work_keys_str_mv | AT lokongmun diaquatrifluoroacetatok2oo246tri2pyridyl135triazinek3n2n1n6manganeseiitrifluoroacetate AT ngseikweng diaquatrifluoroacetatok2oo246tri2pyridyl135triazinek3n2n1n6manganeseiitrifluoroacetate |