Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate

The title stannoxane is a toluene-solvated dimer, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)]·C(7)H(8), the tetra­nuclear mol­ecule lying across a center of inversion. The Sn(4)O(4) framework, whose two independent Sn atoms show trigonal bipyramidal coordination, is essentially planar (r.m.s deviation =...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977629/
https://www.ncbi.nlm.nih.gov/pubmed/21583815
http://dx.doi.org/10.1107/S1600536809015128
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description The title stannoxane is a toluene-solvated dimer, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)]·C(7)H(8), the tetra­nuclear mol­ecule lying across a center of inversion. The Sn(4)O(4) framework, whose two independent Sn atoms show trigonal bipyramidal coordination, is essentially planar (r.m.s deviation = 0.02 Å). One of the two chloro­benzyl groups of the chloridodiorganyltin unit is disordered over two positions with the chloro­phenyl residue refined over two positions in a 50:50 ratio. The solvent mol­ecule is disordered about a twofold axis.
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spelling pubmed-29776292010-12-30 Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title stannoxane is a toluene-solvated dimer, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)]·C(7)H(8), the tetra­nuclear mol­ecule lying across a center of inversion. The Sn(4)O(4) framework, whose two independent Sn atoms show trigonal bipyramidal coordination, is essentially planar (r.m.s deviation = 0.02 Å). One of the two chloro­benzyl groups of the chloridodiorganyltin unit is disordered over two positions with the chloro­phenyl residue refined over two positions in a 50:50 ratio. The solvent mol­ecule is disordered about a twofold axis. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977629/ /pubmed/21583815 http://dx.doi.org/10.1107/S1600536809015128 Text en © Lo and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lo, Kong Mun
Ng, Seik Weng
Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate
title Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate
title_full Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate
title_fullStr Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate
title_full_unstemmed Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate
title_short Dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(IV) toluene solvate
title_sort dichloridoocta­kis(4-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetra­tin(iv) toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977629/
https://www.ncbi.nlm.nih.gov/pubmed/21583815
http://dx.doi.org/10.1107/S1600536809015128
work_keys_str_mv AT lokongmun dichloridooctakis4chlorobenzyldim2hydroxidodim3oxidotetratinivtoluenesolvate
AT ngseikweng dichloridooctakis4chlorobenzyldim2hydroxidodim3oxidotetratinivtoluenesolvate

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