Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)

The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(14)NS(2))(2)], exists in a tetra­hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn—S = 2.521 (2) and Sn⋯S = 2.933 (2) Å]. The Sn atom...

Descripción completa

Detalles Bibliográficos
Autores principales: Baba, Ibrahim, Dzulkefli, Nur Nadia, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977630/
https://www.ncbi.nlm.nih.gov/pubmed/21583816
http://dx.doi.org/10.1107/S1600536809014883
_version_ 1782191150569881600
author Baba, Ibrahim
Dzulkefli, Nur Nadia
Ng, Seik Weng
author_facet Baba, Ibrahim
Dzulkefli, Nur Nadia
Ng, Seik Weng
author_sort Baba, Ibrahim
collection PubMed
description The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(14)NS(2))(2)], exists in a tetra­hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn—S = 2.521 (2) and Sn⋯S = 2.933 (2) Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithio­carbamate unit are disordered about another mirror plane.
format Text
id pubmed-2977630
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29776302010-12-30 Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV) Baba, Ibrahim Dzulkefli, Nur Nadia Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(14)NS(2))(2)], exists in a tetra­hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn—S = 2.521 (2) and Sn⋯S = 2.933 (2) Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithio­carbamate unit are disordered about another mirror plane. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977630/ /pubmed/21583816 http://dx.doi.org/10.1107/S1600536809014883 Text en © Baba et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Baba, Ibrahim
Dzulkefli, Nur Nadia
Ng, Seik Weng
Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)
title Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)
title_full Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)
title_fullStr Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)
title_full_unstemmed Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)
title_short Di-n-butyl­bis(N-n-butyl-N-ethyl­dithio­carbamato-κS)tin(IV)
title_sort di-n-butyl­bis(n-n-butyl-n-ethyl­dithio­carbamato-κs)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977630/
https://www.ncbi.nlm.nih.gov/pubmed/21583816
http://dx.doi.org/10.1107/S1600536809014883
work_keys_str_mv AT babaibrahim dinbutylbisnnbutylnethyldithiocarbamatokstiniv
AT dzulkeflinurnadia dinbutylbisnnbutylnethyldithiocarbamatokstiniv
AT ngseikweng dinbutylbisnnbutylnethyldithiocarbamatokstiniv

Ejemplares similares