Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)

The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra­hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0 (2) to 136.9 (2)...

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Detalles Bibliográficos
Autores principales: Baba, Ibrahim, Akmal, Nor Syaidatul, Awang, Normah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977631/
https://www.ncbi.nlm.nih.gov/pubmed/21583817
http://dx.doi.org/10.1107/S1600536809015116
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author Baba, Ibrahim
Akmal, Nor Syaidatul
Awang, Normah
Ng, Seik Weng
author_facet Baba, Ibrahim
Akmal, Nor Syaidatul
Awang, Normah
Ng, Seik Weng
author_sort Baba, Ibrahim
collection PubMed
description The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra­hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0 (2) to 136.9 (2)°, the covalent Sn—S lengths from 2.529 (1) to 2.544 (1) Å, and the dative Sn←S lengths from 2.831 (1) to 3.042 (1) Å in the five independent mol­ecules comprising the asymmetric unit. Two of the butyl groups were modelled over two positions of equal occupancy. All butyl groups were refined with distance restraints.
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spelling pubmed-29776312010-12-30 Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV) Baba, Ibrahim Akmal, Nor Syaidatul Awang, Normah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra­hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0 (2) to 136.9 (2)°, the covalent Sn—S lengths from 2.529 (1) to 2.544 (1) Å, and the dative Sn←S lengths from 2.831 (1) to 3.042 (1) Å in the five independent mol­ecules comprising the asymmetric unit. Two of the butyl groups were modelled over two positions of equal occupancy. All butyl groups were refined with distance restraints. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977631/ /pubmed/21583817 http://dx.doi.org/10.1107/S1600536809015116 Text en © Baba et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Baba, Ibrahim
Akmal, Nor Syaidatul
Awang, Normah
Ng, Seik Weng
Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)
title Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)
title_full Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)
title_fullStr Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)
title_full_unstemmed Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)
title_short Bis(N-benzyl-N-isopropyl­dithio­carbamato-κS)di-n-butyl­tin(IV)
title_sort bis(n-benzyl-n-isopropyl­dithio­carbamato-κs)di-n-butyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977631/
https://www.ncbi.nlm.nih.gov/pubmed/21583817
http://dx.doi.org/10.1107/S1600536809015116
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