[μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]

The asymmetric unit of the title complex, [Pd(2)(NO(3))(4)(C(58)H(52)N(2)P(4))], contains one half-mol­ecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the cry...

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Autores principales: Jiang, Xuan-Feng, Lian, Heng-Chi, Min, Zhong, Wang, Xiu-Jian, Lin, Jia-Huang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977633/
https://www.ncbi.nlm.nih.gov/pubmed/21583819
http://dx.doi.org/10.1107/S160053680901486X
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author Jiang, Xuan-Feng
Lian, Heng-Chi
Min, Zhong
Wang, Xiu-Jian
Lin, Jia-Huang
author_facet Jiang, Xuan-Feng
Lian, Heng-Chi
Min, Zhong
Wang, Xiu-Jian
Lin, Jia-Huang
author_sort Jiang, Xuan-Feng
collection PubMed
description The asymmetric unit of the title complex, [Pd(2)(NO(3))(4)(C(58)H(52)N(2)P(4))], contains one half-mol­ecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the crystal structure, inter­molecular C—H⋯O inter­actions link the mol­ecules into chains, and π–π contacts between the phenyl rings [centroid–centroid distance = 3.928 (3) Å] may further stabilize the structure.
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spelling pubmed-29776332010-12-30 [μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)] Jiang, Xuan-Feng Lian, Heng-Chi Min, Zhong Wang, Xiu-Jian Lin, Jia-Huang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Pd(2)(NO(3))(4)(C(58)H(52)N(2)P(4))], contains one half-mol­ecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the crystal structure, inter­molecular C—H⋯O inter­actions link the mol­ecules into chains, and π–π contacts between the phenyl rings [centroid–centroid distance = 3.928 (3) Å] may further stabilize the structure. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977633/ /pubmed/21583819 http://dx.doi.org/10.1107/S160053680901486X Text en © Jiang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Xuan-Feng
Lian, Heng-Chi
Min, Zhong
Wang, Xiu-Jian
Lin, Jia-Huang
[μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]
title [μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]
title_full [μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]
title_fullStr [μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]
title_full_unstemmed [μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]
title_short [μ-N,N,N′,N′-Tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) P,P′:P′′,P′′′]bis­[bis­(nitrato-κO)palladium(II)]
title_sort [μ-n,n,n′,n′-tetra­kis(diphenyl­phosphino­meth­yl)benzene-1,4-diamine-κ(4) p,p′:p′′,p′′′]bis­[bis­(nitrato-κo)palladium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977633/
https://www.ncbi.nlm.nih.gov/pubmed/21583819
http://dx.doi.org/10.1107/S160053680901486X
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