1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)

In the title complex, (C(12)H(10)FN(2))(2)[Ni(C(4)N(2)S(2))(2)], the anion lies on an inversion center with the Ni(II) ion coordinated by four S atoms in a slightly distorted square-planar environment. In the unique cation, the dihedral angle between the benzene and pyridine rings is 7.1 (2) Å.

Detalles Bibliográficos
Autores principales: Zhang, Hui, Zhou, Quan, Hu, Fengkai, Xu, Han, Chang, Guanru
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977634/
https://www.ncbi.nlm.nih.gov/pubmed/21583820
http://dx.doi.org/10.1107/S1600536809015360
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author Zhang, Hui
Zhou, Quan
Hu, Fengkai
Xu, Han
Chang, Guanru
author_facet Zhang, Hui
Zhou, Quan
Hu, Fengkai
Xu, Han
Chang, Guanru
author_sort Zhang, Hui
collection PubMed
description In the title complex, (C(12)H(10)FN(2))(2)[Ni(C(4)N(2)S(2))(2)], the anion lies on an inversion center with the Ni(II) ion coordinated by four S atoms in a slightly distorted square-planar environment. In the unique cation, the dihedral angle between the benzene and pyridine rings is 7.1 (2) Å.
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spelling pubmed-29776342010-12-30 1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II) Zhang, Hui Zhou, Quan Hu, Fengkai Xu, Han Chang, Guanru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, (C(12)H(10)FN(2))(2)[Ni(C(4)N(2)S(2))(2)], the anion lies on an inversion center with the Ni(II) ion coordinated by four S atoms in a slightly distorted square-planar environment. In the unique cation, the dihedral angle between the benzene and pyridine rings is 7.1 (2) Å. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977634/ /pubmed/21583820 http://dx.doi.org/10.1107/S1600536809015360 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Hui
Zhou, Quan
Hu, Fengkai
Xu, Han
Chang, Guanru
1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title 1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full 1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_fullStr 1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full_unstemmed 1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_short 1-(2-Fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_sort 1-(2-fluoro­benzyl­ideneamino)pyridinium bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977634/
https://www.ncbi.nlm.nih.gov/pubmed/21583820
http://dx.doi.org/10.1107/S1600536809015360
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AT hufengkai 12fluorobenzylideneaminopyridiniumbis12dicyanoethene12dithiolatonickelateii
AT xuhan 12fluorobenzylideneaminopyridiniumbis12dicyanoethene12dithiolatonickelateii
AT changguanru 12fluorobenzylideneaminopyridiniumbis12dicyanoethene12dithiolatonickelateii

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