catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]

The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro­methyl...

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Detalles Bibliográficos
Autores principales: Jokiniemi, Jonna, Vepsäläinen, Jouko, Ahlgrén, Markku
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977635/
https://www.ncbi.nlm.nih.gov/pubmed/21583821
http://dx.doi.org/10.1107/S160053680901527X
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author Jokiniemi, Jonna
Vepsäläinen, Jouko
Ahlgrén, Markku
author_facet Jokiniemi, Jonna
Vepsäläinen, Jouko
Ahlgrén, Markku
author_sort Jokiniemi, Jonna
collection PubMed
description The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro­methyl­enediphospho­nate ligands into chains in the c-axis direction. These chains are further connected by O—H⋯O hydrogen bonds into a layer-like construction along (100).
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spelling pubmed-29776352010-12-30 catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′] Jokiniemi, Jonna Vepsäläinen, Jouko Ahlgrén, Markku Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro­methyl­enediphospho­nate ligands into chains in the c-axis direction. These chains are further connected by O—H⋯O hydrogen bonds into a layer-like construction along (100). International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977635/ /pubmed/21583821 http://dx.doi.org/10.1107/S160053680901527X Text en © Jokiniemi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jokiniemi, Jonna
Vepsäläinen, Jouko
Ahlgrén, Markku
catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]
title catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]
title_full catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]
title_fullStr catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]
title_full_unstemmed catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]
title_short catena-Poly[[diaqua­cadmium(II)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) O,O′:O′′-[tetra­aqua­cadmium(II)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) O:O′,O′′]
title_sort catena-poly[[diaqua­cadmium(ii)]-μ-(methyl morpholino dichloro­methylene­diphospho­nato)-κ(3) o,o′:o′′-[tetra­aqua­cadmium(ii)]-μ-(methyl morpholino dichloro­methyl­enediphospho­nato)-κ(3) o:o′,o′′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977635/
https://www.ncbi.nlm.nih.gov/pubmed/21583821
http://dx.doi.org/10.1107/S160053680901527X
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