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[1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)

The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol­ecules in the asymmetric unit. The gold(I) centres display a distorted tetra­hedral geometry. The complex is stablized through weak intra­molecular π–π stacking (Cg⋯Cg = 4.1...

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Detalles Bibliográficos
Autores principales: Ioppolo, Joseph A., Clegg, Jack K., Rendina, Louis M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977637/
https://www.ncbi.nlm.nih.gov/pubmed/21583823
http://dx.doi.org/10.1107/S1600536809014937
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author Ioppolo, Joseph A.
Clegg, Jack K.
Rendina, Louis M.
author_facet Ioppolo, Joseph A.
Clegg, Jack K.
Rendina, Louis M.
author_sort Ioppolo, Joseph A.
collection PubMed
description The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol­ecules in the asymmetric unit. The gold(I) centres display a distorted tetra­hedral geometry. The complex is stablized through weak intra­molecular π–π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter­actions (H⋯Cg = 3.21 Å). Adjacent mol­ecules inter­act through C—H⋯π (H⋯Cg = 2.88 Å) and B—H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent mol­ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35.
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spelling pubmed-29776372010-12-30 [1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1) Ioppolo, Joseph A. Clegg, Jack K. Rendina, Louis M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol­ecules in the asymmetric unit. The gold(I) centres display a distorted tetra­hedral geometry. The complex is stablized through weak intra­molecular π–π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter­actions (H⋯Cg = 3.21 Å). Adjacent mol­ecules inter­act through C—H⋯π (H⋯Cg = 2.88 Å) and B—H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent mol­ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977637/ /pubmed/21583823 http://dx.doi.org/10.1107/S1600536809014937 Text en © Ioppolo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ioppolo, Joseph A.
Clegg, Jack K.
Rendina, Louis M.
[1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)
title [1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)
title_full [1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)
title_fullStr [1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)
title_full_unstemmed [1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)
title_short [1,2-Bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) P,P′]gold(I)–dichloro­methane–water (2/1/1)
title_sort [1,2-bis(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) p,p′][7,8-bis­(di­phenyl­phosphino)-7,8-dicarba-nido-undeca­borato-κ(2) p,p′]gold(i)–dichloro­methane–water (2/1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977637/
https://www.ncbi.nlm.nih.gov/pubmed/21583823
http://dx.doi.org/10.1107/S1600536809014937
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