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[1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2) P,P′]gold(I)–dichloromethane–water (2/1/1)
The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex molecules in the asymmetric unit. The gold(I) centres display a distorted tetrahedral geometry. The complex is stablized through weak intramolecular π–π stacking (Cg⋯Cg = 4.1...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977637/ https://www.ncbi.nlm.nih.gov/pubmed/21583823 http://dx.doi.org/10.1107/S1600536809014937 |
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author | Ioppolo, Joseph A. Clegg, Jack K. Rendina, Louis M. |
author_facet | Ioppolo, Joseph A. Clegg, Jack K. Rendina, Louis M. |
author_sort | Ioppolo, Joseph A. |
collection | PubMed |
description | The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex molecules in the asymmetric unit. The gold(I) centres display a distorted tetrahedral geometry. The complex is stablized through weak intramolecular π–π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face interactions (H⋯Cg = 3.21 Å). Adjacent molecules interact through C—H⋯π (H⋯Cg = 2.88 Å) and B—H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent molecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35. |
format | Text |
id | pubmed-2977637 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29776372010-12-30 [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2) P,P′]gold(I)–dichloromethane–water (2/1/1) Ioppolo, Joseph A. Clegg, Jack K. Rendina, Louis M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex molecules in the asymmetric unit. The gold(I) centres display a distorted tetrahedral geometry. The complex is stablized through weak intramolecular π–π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face interactions (H⋯Cg = 3.21 Å). Adjacent molecules interact through C—H⋯π (H⋯Cg = 2.88 Å) and B—H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent molecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977637/ /pubmed/21583823 http://dx.doi.org/10.1107/S1600536809014937 Text en © Ioppolo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ioppolo, Joseph A. Clegg, Jack K. Rendina, Louis M. [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2) P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2) P,P′]gold(I)–dichloromethane–water (2/1/1) |
title | [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2)
P,P′]gold(I)–dichloromethane–water (2/1/1) |
title_full | [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2)
P,P′]gold(I)–dichloromethane–water (2/1/1) |
title_fullStr | [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2)
P,P′]gold(I)–dichloromethane–water (2/1/1) |
title_full_unstemmed | [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2)
P,P′]gold(I)–dichloromethane–water (2/1/1) |
title_short | [1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2)
P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2)
P,P′]gold(I)–dichloromethane–water (2/1/1) |
title_sort | [1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ(2)
p,p′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ(2)
p,p′]gold(i)–dichloromethane–water (2/1/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977637/ https://www.ncbi.nlm.nih.gov/pubmed/21583823 http://dx.doi.org/10.1107/S1600536809014937 |
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