Cargando…
Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN (1))nickel(II)
The title Ni(II) complex, [Ni(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom on an inversion center. The molecule contains two 4-methylaminobenzoate (MAB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. Th...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977638/ https://www.ncbi.nlm.nih.gov/pubmed/21583824 http://dx.doi.org/10.1107/S1600536809015633 |
_version_ | 1782191152498212864 |
---|---|
author | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | The title Ni(II) complex, [Ni(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom on an inversion center. The molecule contains two 4-methylaminobenzoate (MAB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 2.09 (14)°, while the pyridine and benzene rings are oriented at a dihedral angle of 66.15 (4)°. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
format | Text |
id | pubmed-2977638 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29776382010-12-30 Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN (1))nickel(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Ni(II) complex, [Ni(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom on an inversion center. The molecule contains two 4-methylaminobenzoate (MAB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 2.09 (14)°, while the pyridine and benzene rings are oriented at a dihedral angle of 66.15 (4)°. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977638/ /pubmed/21583824 http://dx.doi.org/10.1107/S1600536809015633 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN (1))nickel(II) |
title | Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_full | Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_fullStr | Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_full_unstemmed | Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_short | Diaquabis(4-methylaminobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_sort | diaquabis(4-methylaminobenzoato-κo)bis(nicotinamide-κn
(1))nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977638/ https://www.ncbi.nlm.nih.gov/pubmed/21583824 http://dx.doi.org/10.1107/S1600536809015633 |
work_keys_str_mv | AT hokelektuncer diaquabis4methylaminobenzoatokobisnicotinamidekn1nickelii AT dalhakan diaquabis4methylaminobenzoatokobisnicotinamidekn1nickelii AT tercanbarıs diaquabis4methylaminobenzoatokobisnicotinamidekn1nickelii AT aybirdiozgur diaquabis4methylaminobenzoatokobisnicotinamidekn1nickelii AT necefogluhacali diaquabis4methylaminobenzoatokobisnicotinamidekn1nickelii |