Cargando…

Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)

The title Zn(II) complex, [Zn(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Zn atom on an inversion center. The mol­ecule contains two 2-bromo­benzoate (BB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four...

Descripción completa

Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Özbek, F. Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977639/
https://www.ncbi.nlm.nih.gov/pubmed/21583825
http://dx.doi.org/10.1107/S1600536809015645
Descripción
Sumario:The title Zn(II) complex, [Zn(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Zn atom on an inversion center. The mol­ecule contains two 2-bromo­benzoate (BB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 31.14 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.54 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into infinite chains. A weak C—H⋯π inter­action is also present.