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Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)

The title Zn(II) complex, [Zn(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Zn atom on an inversion center. The mol­ecule contains two 2-bromo­benzoate (BB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Özbek, F. Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977639/
https://www.ncbi.nlm.nih.gov/pubmed/21583825
http://dx.doi.org/10.1107/S1600536809015645
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The title Zn(II) complex, [Zn(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Zn atom on an inversion center. The mol­ecule contains two 2-bromo­benzoate (BB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 31.14 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.54 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into infinite chains. A weak C—H⋯π inter­action is also present.
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spelling pubmed-29776392010-12-30 Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II) Hökelek, Tuncer Dal, Hakan Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Zn(II) complex, [Zn(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Zn atom on an inversion center. The mol­ecule contains two 2-bromo­benzoate (BB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 31.14 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.54 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into infinite chains. A weak C—H⋯π inter­action is also present. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977639/ /pubmed/21583825 http://dx.doi.org/10.1107/S1600536809015645 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)
title Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)
title_full Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)
title_fullStr Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)
title_full_unstemmed Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)
title_short Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))zinc(II)
title_sort diaqua­bis(2-bromo­benzoato-κo)bis­(nicotinamide-κn (1))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977639/
https://www.ncbi.nlm.nih.gov/pubmed/21583825
http://dx.doi.org/10.1107/S1600536809015645
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